Инд. авторы:	Kaneva E., Radomskaya T., Shendrik R., Chubarov V., Danilovsky V.
Заглавие:	Potassic-Hastingsite from the Kedrovy District (East Siberia, Russia): Petrographic Description, Crystal Chemistry, Spectroscopy, and Thermal Behavior
Библ. ссылка:	Kaneva E., Radomskaya T., Shendrik R., Chubarov V., Danilovsky V. Potassic-Hastingsite from the Kedrovy District (East Siberia, Russia): Petrographic Description, Crystal Chemistry, Spectroscopy, and Thermal Behavior // MINERALS. - 2021. - Vol.11. - Iss. 10. - Art.1049.
Внешние системы:	DOI: 10.3390/min11101049; РИНЦ: 47105167; WoS: 000712681600001;
Реферат:	eng: In this work we report on a petrographic, crystal-chemical, and optical characterization, obtained from different analytical methods, of amphibole species. Potassic-hastingsite, ideally (KCa2)-K-A-Ca-B(C)(Fe42+Fe3+)(T)(Si6Al2)O-22(W)(OH)(2), has been found in the Kedrovy district (East Siberia, Russia). The sample occurs as well-formed and large radially radiant aggregates of dark green, almost black crystals. The unit cell dimensions are a = 9.9724(3) & ANGS;, b = 18.2968(4) & ANGS;, c = 5.3573(1) & ANGS;, beta = 104.945(3)& DEG;, V = 944.44(4) & ANGS;(3), Z = 2. Site populations were determined by combining single-crystal structure refinement and electron probe microanalysis, and Fe3+/Fe2+ ratio was obtained from X-ray fluorescence analysis. Infrared, diffuse light UV/Vis/NIR absorption, and electron spin resonance spectra are presented and discussed. A thermoelastic behavior of a powder of potassic-hastingsite was studied by in situ high-temperature X-ray diffraction. A thermal expansion and subsequent significant contraction in the unit cell volume during a high-temperature X-ray powder diffraction experiment is observed as a consequence of the deprotonation process, which is locally balanced via oxidation of Fe2+. According to the data obtained for potassic-hastingsite, these processes occur within 400-600 & DEG;C. The thermal expansion of the mineral is anisotropic; the thermal expansivity coefficients alpha(a):alpha(b):alpha(c) (x10(-6)) = -18.06:9.59:-1.09 at 400 & DEG;C, -26.15:-1.52:2.22 at 600 & DEG;C and 23.77:-25.06:42.08 at 750 & DEG;C.
Ключевые слова:	CHLORINE; DEPROTONATION; AMPHIBOLES; SKARN; FE OXIDATION; ABSORPTION-SPECTRA; MAGNESIO-HASTINGSITE; BOND-VALENCE PARAMETERS; thermal behavior; absorption spectroscopy; electron spin resonance; IR spectroscopy; crystal chemistry; mineral associations; petrography; amphiboles; potassic-hastingsite; HIGH-TEMPERATURE BEHAVIOR; POTASSICHASTINGSITE;
Издано:	2021
Физ. характеристика:	1049
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