Инд. авторы:	Goryainov S.V., Krylova S.N., Borodina U.O, Krylov A.S.
Заглавие:	Dynamical Immiscibility of Aqueous Carbonate Fluid in the Shortite-Water System at High-Pressure-Temperature Conditions
Библ. ссылка:	Goryainov S.V., Krylova S.N., Borodina U.O, Krylov A.S. Dynamical Immiscibility of Aqueous Carbonate Fluid in the Shortite-Water System at High-Pressure-Temperature Conditions // Journal of Physical Chemistry C. - 2021. - Vol.125. - Iss. 33. - P.18501-18509. - ISSN 1932-7447. - EISSN 1932-7455.
Внешние системы:	DOI: 10.1021/acs.jpcc.1c05077; РИНЦ: 47035071; WoS: 000692021300045;
Реферат:	eng: Anhydrous carbonate shortite, Na2Ca2(CO3)(3), compressed in water at high pressure-temperature (up to 5 GPa, 350 degrees C) was studied by Raman spectroscopy. At 3.2 GPa and 250 degrees C, shortite begins to dissolve, followed by crystallization of aragonite and aragonite'. The unusual behavior of aqueous carbonate fluid was observed at 4.8 GPa and 300-350 degrees C. This process is characterized by the active formation of microbubbles within 2-60 s that are inserted one into another. Microbubbles are considered to be a result of the two immiscible fluid stratification. This dynamical immiscibility of the fluid accompanies the appearance of several crystalline carbonates and organic molecular crystals. Na-formate and some polymorphs of Ca-formate were observed.
Ключевые слова:	CALCITE; CRYSTAL; BEHAVIOR; NA2CO3-CACO3; RAMAN-SPECTRA; SODIUM FORMATE; SIMULTANEOUSLY HIGH-PRESSURE; PHASE-RELATIONS; GPA;
Издано:	2021
Физ. характеристика:	с.18501-18509
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