Инд. авторы: Kuznetsov A.B., Kokh K.A., Kononova N.G., Shevchenko V.S., Rashchenko S.V., Ezhov D.M., Jamous A.Y., Bolatov A., Uralbekov B.M., Svetlichnyi V.A., Kokh A.E.
Заглавие: Polymorphism in SmSc3(BO3)(4): Crystal structure, luminescent and SHG properties
Библ. ссылка: Kuznetsov A.B., Kokh K.A., Kononova N.G., Shevchenko V.S., Rashchenko S.V., Ezhov D.M., Jamous A.Y., Bolatov A., Uralbekov B.M., Svetlichnyi V.A., Kokh A.E. Polymorphism in SmSc3(BO3)(4): Crystal structure, luminescent and SHG properties // Journal of Alloys and Compounds. - 2021. - Vol.851. - Art.156825. - ISSN 0925-8388. - EISSN 1873-4669.
Внешние системы: DOI: 10.1016/j.jallcom.2020.156825; WoS: 000579868900065;
Реферат: eng: Low temperature C2/c and high temperature P321 modifications of SmxSc4-x(BO3)(4) solid solutions were grown from LiBO2-LiF flux. These borates have typical luminescence for Sm3+ containing crystals with the two strongest peaks at 602 and 645 nm, which correspond to (4)G(5/2) -> H-6(7/2), H-6(5/2) electron transitions. In addition, the compounds were characterized by IR and Raman spectroscopy. SHG intensity for trigonal modification was found to be three times higher than that of KDP revealing its high potential for various NLO applications. (C) 2020 Elsevier B.V. All rights reserved.
Ключевые слова: SERIES; GROWTH; ALKALINE-EARTH; ENERGY-TRANSFER; SPECTROSCOPIC PROPERTIES; DOPED INORGANIC MATERIALS; UV; Solid state synthesis; Crystal growth; SHG; Luminescence; Structure; Rare earth borate; COOPERATIVE OPTICAL-TRANSITIONS; GLASS;
Издано: 2021
Физ. характеристика: 156825