Инд. авторы: | Murzin V., Chudnenko K., Palyanova G., Varlamov D. |
Заглавие: | Formation of Au-Bearing Antigorite Serpentinites and Magnetite Ores at the Massif of Ophiolite Ultramafic Rocks: Thermodynamic Modeling |
Библ. ссылка: | Murzin V., Chudnenko K., Palyanova G., Varlamov D. Formation of Au-Bearing Antigorite Serpentinites and Magnetite Ores at the Massif of Ophiolite Ultramafic Rocks: Thermodynamic Modeling // MINERALS. - 2019. - Vol.9. - Iss. 12. - Art.758. |
Внешние системы: | DOI: 10.3390/min9120758; РИНЦ: 42933634; РИНЦ: 43223223; WoS: 000506636900042; |
Реферат: | eng: We constructed thermodynamic models of the formation of two types of gold-ore mineralization at the Kagan ultramafic massif in the Southern Urals (Russia). The first type of gold-mineralization is widely spread at the massif in the tectonic zones of schistose serpentinites containing typically <= 0.1 ppm Au. The second type of gold-ore mineralization is represented by veined massive, streaky and impregnated magnetite ores in contact with serpentinites. It contains to 5 vol.% sulfides and 0.2-1.2 ppm Au. Our thermodynamic calculations explain the formation of two types of gold-ore mineralization in the bedrocks of ultramafic massifs. Metamorphic water, which is the result of the dehydration of early serpentinites (middle Riphean) during high-temperature regional metamorphism (700 degrees C, 10 kbar) (late Precambrian), is considered as the source of ore-bearing fluid in the models. The metasomatic interaction of metamorphic fluid with serpentinites is responsible for the gold-poor mineralization of the 1st type at T = 450-250 degrees C and P = 2.5-0.5 kbar. The hydrothermal gold-rich mineralization of the 2nd type was formed during mixing of metamorphic and meteoric fluids at T = 500-400 degrees C and P = 2-3 kbar and discharge of mixed fluid in the open space of cracks in serpentinites. The model calculations showed that the dominant forms of gold transport in fluids with pH = 3-5 are AuCl2- complexes (>= 450 degrees C) and, as the temperature decreases, AuHS0, or AuOH0. Mineral associations obtained in model calculations are in general similar to the observed natural types of gold mineralization.
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Ключевые слова: | ORIGIN; MINERALS; TEMPERATURES; GOLD; O-H; SOLID-SOLUTIONS; TRANSPORT-PROPERTIES; HIGH-PRESSURES; SOLUBILITIES; thermodynamic modeling; native gold; gold mineralization; magnetite veins; antigorite serpentinites; Southern Urals; Kagan ultramafic massif; fluid regime; FLUID; |
Издано: | 2019 |
Физ. характеристика: | 758 |