Инд. авторы:	Rezvukhina O.V, Korsakov A.V., Rezvukhin D.I., Zamyatin D.A., Zelenovskiy P.S., Greshnyakov E.D., Shur V.Y.
Заглавие:	A combined Raman spectroscopy, cathodoluminescence, and electron backscatter diffraction study of kyanite porphyroblasts from diamondiferous and diamond-free metamorphic rocks (Kokchetav massif)
Библ. ссылка:	Rezvukhina O.V, Korsakov A.V., Rezvukhin D.I., Zamyatin D.A., Zelenovskiy P.S., Greshnyakov E.D., Shur V.Y. A combined Raman spectroscopy, cathodoluminescence, and electron backscatter diffraction study of kyanite porphyroblasts from diamondiferous and diamond-free metamorphic rocks (Kokchetav massif) // Journal of Raman Spectroscopy. - 2020. - ISSN 0377-0486. - EISSN 1097-4555.
Внешние системы:	DOI: 10.1002/jrs.5757; РИНЦ: 43224386; РИНЦ: 45483694; SCOPUS: 2-s2.0-85077028521; WoS: 000504004600001;
Реферат:	eng: A series of precise nondestructive analytical methods (Raman spectroscopy, cathodoluminescence, and EBSD-electron backscatter diffraction) has been employed to investigate the internal textures of kyanite porphyroblasts from diamondiferous and diamond-free ultrahigh-pressure metamorphic rocks (Kokchetav massif, Northern Kazakhstan). Such internal kyanite characteristics as twinning, radial fibrous pattern, and spotty zoning were identified by means of Raman and cathodoluminescence imaging, whereas an intergrowth of two kyanite crystals was distinguished only by Raman imaging. The EBSD analysis recorded an similar to 10-25 degrees changing of orientations along the elongation in the investigated kyanite porphyroblasts. The absence of a radial fibrous pattern and a spotty zoning on the EBSD maps indicates that these textures are not related to variations in crystallographic orientation. The absence of clear zoning patterns (cores, mantles, and rims) on the Raman, cathodoluminescence, or EBSD maps of the kyanite porphyroblasts indicates the rapid single-stage formation of these porphyroblasts near the peak metamorphic conditions and the lack of recrystallization processes. The obtained results provide important implications for deciphering of mineral internal textures, showing that the data obtained by cathodoluminescence mapping can be clearly reproduced by Raman imaging, with the latter method occasionally being even more informative. This observation is of significant importance for the study of minerals that are unexposed on a thin section surface or Fe- and Ni-rich minerals that do not show luminescence emission. The combination of the Raman spectroscopic, cathodoluminescence, and EBSD techniques may provide better spatial resolution for distinguishing different domains and textural peculiarities of mineral than the selective application of individual approaches.
Ключевые слова:	EBSD; Kokchetav massif; Raman spectroscopy; UHPM rocks; ULTRAHIGH-PRESSURE METAMORPHISM; HOST-INCLUSION SYSTEMS; MULTIPLE ZIRCON GROWTH; DISORDERED GRAPHITE; COESITE INCLUSIONS; CONTINENTAL-CRUST; WESTERN ALPS; 1ST RECORD; K-CYMRITE; EXPERIMENTAL CONSTRAINTS; cathodoluminescence;
Издано:	2020
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