Инд. авторы:	Kosyakov V.I., Sinyakova E.F., Kokh K.A.
Заглавие:	Sequential crystallization of four phases from melt on the polythermal section of the Cu–Fe–Ni–S system
Библ. ссылка:	Kosyakov V.I., Sinyakova E.F., Kokh K.A. Sequential crystallization of four phases from melt on the polythermal section of the Cu–Fe–Ni–S system // Journal of Thermal Analysis and Calorimetry. - 2019. - ISSN 1388-6150. - EISSN 1572-8943.
Внешние системы:	DOI: 10.1007/s10973-019-08701-y; РИНЦ: 41642001; РИНЦ: 43206702; SCOPUS: 2-s2.0-85071484102; WoS: 000519668200002;
Реферат:	eng: Directional crystallization and thermal analysis were used to construct a nontrivial polythermal section of the solid–liquid diagram of the Cu–Fe–Ni–S system. We have carried out directional crystallization of melt of the following composition (in mol%): Fe 32.06, Ni 1.70, Cu 15.80 and S 50.4. Results of microscopic and electron microprobe analyses showed that the grown ingot consists of five zones with different chemical and phase compositions. They formed during sequential crystallization of four phases from the following melt: monosulfide solid solution mss, non-stoichiometric isocubanite icb* and two intermediate solid solutions iss1 and iss2 with a similar composition. It was found that the chemical composition of the phases and the melt changes during crystallization. Thermal analysis of specially synthesized samples along the crystallization path was performed. The position of the liquidus and solidus in the 4D space was determined (T, xNi, xCu, xFe). These data were used for constructing the polythermal sections of the phase diagram along the crystallization path. © 2019, Akadémiai Kiadó, Budapest, Hungary.
Ключевые слова:	Solid diagrams; Polythermal sections; Polythermal cross section; Monosulfide solid solutions; Intermediate solid solutions; Directional crystallization; Chemical compositions; Chemical and phase compositions; Solid solutions; Solidification; Electron probe microanalysis; Differential thermal analysis; System Cu–Fe–Ni–S; Polythermal cross section; Liquid–solid diagram; DTA; Directional solidification; Thermoanalysis;
Издано:	2019