Инд. авторы: | Plotnikov V.A., Dem'yanov B.F., Yeliseeyev A.P, Makarov S.V., Zyryanova A.I. |
Заглавие: | Structural state of diamond-like amorphous carbon films, obtained by laser evaporation of carbon target |
Библ. ссылка: | Plotnikov V.A., Dem'yanov B.F., Yeliseeyev A.P, Makarov S.V., Zyryanova A.I. Structural state of diamond-like amorphous carbon films, obtained by laser evaporation of carbon target // Diamond and Related Materials. - 2019. - Vol.91. - P.225-229. - ISSN 0925-9635. - EISSN 1879-0062. |
Внешние системы: | DOI: 10.1016/j.diamond.2018.11.022; РИНЦ: 38640120; SCOPUS: 2-s2.0-85057861066; WoS: 000457660500028; |
Реферат: | eng: A homogeneous diamond-like film was obtained on an area of 75 x 25 mm(2). Study of the film structure, using transmission electron microscopy and Raman spectroscopy, showed a mixture of carbon atoms with sp(2)- and sp(3)-bonds. Structure of carbon film is determined by the presence of randomly oriented carbon clusters bound by diamond sp(3)-bonds (tetrahedral amorphous carbon, to-C). Electron diffraction patterns demonstrate strongly distorted interfacial distances. Raman spectra show that there are carbon atoms with graphite sp(2)-bonds in the film, but a signal of graphite crystal lattice is absent in electron diffraction: This implies that hexagonal units are not shaped into a graphite crystal lattice. Broad D-band in Raman spectra shows strongly distorted carbon bonds in graphite. If diamond phase dominates, the space between diamond clusters is filled with carbon atoms with sp(2)-bonds (turbostratic structure). Thus, diamond areas are bound into a single discontinuous aggregate of carbon diamond-like film.
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Ключевые слова: | Nanotechnology; Microstructure; DEPOSITION; Pulsed laser deposition; Amorphous carbon; Vibrational properties characterization; SUBSTRATE-TEMPERATURE; |
Издано: | 2019 |
Физ. характеристика: | с.225-229 |