Crystal formation of Cu-Mn-containing oxides and oxyborates in bismuth-boron fluxes diluted by MoO3 and Na2CO3

Moshkina E.; Seryotkin Y.; Bovina A.; Molokeev M.; Eremin E.; Belskaya N.; Bezmaternykh L.

doi:10.1016/j.jcrysgro.2018.09.011

Инд. авторы:	Moshkina E., Seryotkin Y., Bovina A., Molokeev M., Eremin E., Belskaya N., Bezmaternykh L.
Заглавие:	Crystal formation of Cu-Mn-containing oxides and oxyborates in bismuth-boron fluxes diluted by MoO3 and Na2CO3
Библ. ссылка:	Moshkina E., Seryotkin Y., Bovina A., Molokeev M., Eremin E., Belskaya N., Bezmaternykh L. Crystal formation of Cu-Mn-containing oxides and oxyborates in bismuth-boron fluxes diluted by MoO3 and Na2CO3 // Journal of Crystal Growth. - 2018. - Vol.503. - P.1-8. - ISSN 0022-0248. - EISSN 1873-5002.
Внешние системы:	DOI: 10.1016/j.jcrysgro.2018.09.011; РИНЦ: 35731535; SCOPUS: 2-s2.0-85053797039; WoS: 000446880400001;
Реферат:	eng: The high-temperature crystallizing phases of fluxes (molten solutions) based on Bi2O3:MoO3 = 1:3 and diluted by Na2CO3 and B2O3 (under varying of Na2CO3:B2O3), and by CuO and Mn2O3 (0 <= Mn2O3:CuO <= 5) are studied. The conditions of the stable crystallization of Mn1-x2+CuxMoO4, Mn23+O3, Mn2+Mn23+O4, Mn1-x2+CuxMn3+BO4 and Mn2-x2+CuxMn3+BO5 have been found. The influence of MoO3 and Na2CO3 to the crystallization processes of Mn2+ - and Mn3+ -containing Mn1-x2+CuxMoO4 and Mn2+Mn23+O4 and Mn23+O3 are clarified. The occurrence of the chemical bonds of these types at the crystallization of Mn-heterovalent Mn1-x2+CuxMn3+BO4 and Mn2-x2+CuxMn3+BO5 oxyborates is studied. Single crystal growth techniques of these oxyborates are suggested. The results of the structural and magnetic characterization of some discussed compounds are presented.
Ключевые слова:	LUDWIGITE; GROWTH; SINGLE-CRYSTALS; Manganites; Single crystal growth; Growth from solutions; Characterization; Magnetic materials; MAGNETISM;
Издано:	2018
Физ. характеристика:	с.1-8
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