Инд. авторы: Gustaytis M.A., Myagkaya I.N., Chumbaev A.S.
Заглавие: Hg in snow cover and snowmelt waters in high-sulfide tailing regions (Ursk tailing dump site, Kemerovo region, Russia)
Библ. ссылка: Gustaytis M.A., Myagkaya I.N., Chumbaev A.S. Hg in snow cover and snowmelt waters in high-sulfide tailing regions (Ursk tailing dump site, Kemerovo region, Russia) // CHEMOSPHERE. - 2018. - Vol.202. - P.446-459. - ISSN 0045-6535.
Внешние системы: DOI: 10.1016/j.chemosphere.2018.03.076; РИНЦ: 35495969; PubMed: 29579679; SCOPUS: 2-s2.0-85047406607; WoS: 000430882700050;
Реферат: eng: Gold-bearing polymetallic Cu-Zn deposits of sulphur-pyrite ores were discovered in the Novo-Ursk region in the 1930s. The average content of mercury (Hg) was approximately 120 gig at the time. A comprehensive study of Hg distribution in waste of metal ore enrichment industry was carried out in the cold season on the tailing dump site and in adjacent areas. Mercury concentration in among snow particulate, dissolved and colloid fractions was determined. The maximal Hg content in particulate fraction from the waste tailing site ranged 230-573 mu g/g. Such indices as the frequency of aerosol dust deposition events per units of time and area, enrichment factor and the total load allowed to establish that the territory of the tailing waste dump site had a snow cover highly contaminated with dust deposited at a rate of 247-480 mg/(m(2). day). Adjacent areas could be considered as area with low Hg contamination rate with average deposition rate of 30 mg/(m(2). day). The elemental composition of the aerosol dust depositions was determined as well, which allowed to reveal the extent of enrichment waste dispersion throughout adjacent areas. The amount of Hg entering environment with snowmelt water discharge was estimated. As a result of snowmelting, in 2014 the nearest to the dump site hydrographic network got Hg as 7.1 g with colloids and as 5880 g as particles. The results obtained allowed to assess the degree of Hg contamination of areas under the impact of metal enrichment industry. (C) 2018 Elsevier Ltd. All rights reserved.
Ключевые слова: SURFACE SNOW; OXIDATION ZONE; POTENTIAL SOURCE; CRYOGEOCHEMICAL PROCESSES; ARCTIC-OCEAN; TRACE-ELEMENTS; ATMOSPHERIC MERCURY; ACID-MINE DRAINAGE; Snowmelt waters; Snow; Hg; High-sulfide Gold-bearing tailings; HEAVY-METALS; FRENCH ALPS;
Издано: 2018
Физ. характеристика: с.446-459
Цитирование: 1. AMAP, Persistent Toxic Substances, Food Security and Indigenous Peoples of the Russian North. Final Report, 2004, Arctic Monitoring and Assessment Programme (AMAP), Oslo, 181. 2. Ariya, P., Dastoor, A., Amyot, M., Schroeder, W., Barrie, L., Anlauf, K., Raofie, F., Ryzhkov, A., Davignon, D., Lalonde, J., Steffen, A., The Arctic: a sink for mercury. Tellus B 56:5 (2004), 397–403. 3. Agency for Toxic Substances and Disease Registry (ATSDR), Toxicological Profile for Mercury. 1999, US Public Health Service, Department of Health and Human Services, Atlanta, Georgia, USA. 4. Auld, R.R., Myre, M., Mykytczuk, N.C.S., Leduc, L.G., Merritt, T.J.S., Characterization of the acid mine drainage microbial community using culturing and direct sequencing techniques. J. Microbiol. Meth. 93:2 (2013), 108–115. 5. Barkay, T., Gillman, M., Turner, R., Effects of dissolved organic carbon and Salinity on bioavailability of mercury. Appl. Environ. Microbiol. 63:11 (1997), 4267–4271. 6. Bessonenko, V.V., Vinkim, M.K., Kuznetsov, A.M., Geologicalmap of the USSR. Scale 1:200,000, Series Kuzbass, Sheet N-45-XIV, Explanatory Note, Moscow, 1970 (in Russian). 7. Blowes, D.W., Ptacek, C.J., Jambor, J.L., Remediation and prevention of low-quality drainage from tailings impoundments. Jambor, J.L., Blowes, D.W., (eds.) Short Course Handbook on Environmental Geochemistry of Sulfide Mine-waters: Mineralogical Association of Canada, 22, 1994, 365–380 Waterloo Ontario. 8. Blowes, D.W., Ptacek, C.J., Jambor, J.L., Weisener, C.G., The geochemistry of acid mine drainage. Ref. Module Earth Syst. Environ. Sci. Treatise Geochem. 9 (2003), 149–204. 9. Boev, V.A., Lezhnina, A.A., Heavy metals in the snow cover of the Tyumen region//Bulletin of the Tyumen State University. Ecol. Geochem.(7), 2012, 41–48 (in Russian). 10. Bortnikova, S.B., Airiyants, A.A., Kolonin, G.R., Lazareva, E.V., Geochemistry and mineralogy of technogene deposits at the Salair mining and beneficiation works. Geochem. Int. 34:2 (1996), 153–166. 11. Bortnikova, S.B., Gaskova, O.L., Bessonova, E.P., Geochemistry of Technogenic Systems. 2006, Geo, Novosibirsk 169 p. (in Russian). 12. Campbell, L.M., Norstrom, R.J., Hobson, K.A., Muir, D., G., C., Backus, S., Fisk, A.T., Mercury and other trace elements in a pelagic Arctic marine food web (Northwater Polynya, Baffin Bay). Sci. Total Environ., 2005, 247–263. 13. Cello, V., Lean, D.R.S., Scott, S.L., Abiotic methylation of mercury in the aquatic environment. Sci. Total Environ. 368 (2006), 126–137. 14. Chumbaev, A.S., Tanasienko, A.A., Measuring snowmelt in Siberia: Causes, process and Consequences. Novel Methods for Monitoring and Managing Land and Water Resources in Siberia, 2016, Springer, 213–231. 15. Colbeck, S.C., A simulation of the enrichment of atmospheric pollutants in snow cover runoff. Water Resour. Res. 17 (1981), 1383–1388. 16. Colbeck, S.C., Air movement in snow due to windpumping. J. Glaciol. 35 (1989), 209–213. 17. Daly, G.L., Wania, F., Simulating the influence of snow on the fate of organic compounds. Environ. Sci. Technol. 38 (2004), 4176–4186. 18. Dastoor, A., Durnford, D., Arctic Ocean: is it a sink or a source of atmospheric mercury. Environ. Sci. Technol. 48:3 (2014), 1707–1717. 19. Dastoor, A., Ryzhkov, A., Durnford, D., Lehnherr, I., Steffen, A., Morrison, H., Atmospheric mercury in the Canadian arctic. Part II: insight from modeling. Sci. Total Environ. 509 (2015), 16–27. 20. Dold, B., Fontbote, L., A mineralogical and geochemical study of element mobility in sulfide mine tailings of Fe oxide Cu–Au deposits from the Punta del Cobre belt, northern Chile. Chem. Geol. 189:3–4 (2002), 135–163. 21. Dommergue, A., Ferrar, i.C.P., Poissant, L., Gauchard, P.-A., Boutron, C.F., Diumal cycles mercury within the snowpack at Kuujjuarapik/Whapmagoostui, Quebec, Canada. Environ. Sci. Techonol. 37 (2003), 3289–3297. 22. Drab, E., Gaudichet, A., Jaffrezo, J.L., Colin, J.L., Mineral particles content in recent snow at Summit (Greenland). Atmos. Environ. 36 (2002), 5365–5376. 23. Dutova, E.M., Bukaty, M.B., Nevol'ko, A.I., Pokrovsky, D.S., Shvartsev, S.L., Hydrogenic concentration of gold in alluvial placers of the Egor'evsk area (Salair). Russ. Geol. Geophys. 47:3 (2006), 364–376 (in Russian). 24. Elberling, B., Environmental controls of the seasonal variation ia oxygen uptake in sulfidic tailings deposited in a permafrost-affected area. Water Resour. Res. 37:1 (2001), 99–107. 25. Ethier, M.-P., Bussière, B., Benzaazoua, M., Garneau, P., Effect of temperature on the weathering of various waste rock types from the Raglan Mine. Cold Reg. Eng. Sustain. Infrastr. Develop. Chang. Cold Environ., 2012, 800–810. 26. Fain, X., Grangeon, S., Bahlmann, E., Johannes, F., Obris, t.D., Dommergue, A., Ferrari, C.P., Cairns, W., Ebinghaus, R., Barbante, C., Cescon, P., Boutron, C., Diurnal production of gaseous mercury in the alpine snowpack before snowmelt. J. Geophys. Res., 112, 2007, D21311, 10.1029/2007JD008520. 27. Ferrar, i.C.P., Dommergue, A., Veysseyre, A., Planchon, F., Boutron, C.F., Mercury speciation in the French seasonal snow cover. Sci. Total Environ. 287 (2002), 61–69. 28. Filimonenko, E.A., Talovskaya, A.V., Yazikov, E.G., Chumak, Y.V., Ilenok, S.S., Mineral composition of solid aerosols particles in impact zones of Tomsk's industrial enterprises. Fundam. Res. 8 (2013), 760–765. 29. Filimonenko, E.A., Lyapina, E.E., Talovskaya, A.V., Parygina, I.A., Eco-geochemical peculiarities of mercury content in solid residue of snow in the industrial enterprises impacted areas of Tomsk. Proc. SPIE 9292, 20th International Symposium on Atmospheric and Ocean Optics: Atmospheric Physics, vol. 929231, 2014, 10.1117/12.2075637. 30. Fisher, J.A., Jacob, D.J., Soerensen, A.L., Amos, H.M., Steffen, A., Sunderland, E.M., Riverine source of Arctic Ocean mercury inferred from atmospheric observations. Nat. Geosci. 5:7 (2012), 499–504. 31. Fitzgerald, W.F., Lamborg, C.H., Hammerschmidt, C.R., Marine biogeochemical cycling of mercury. Chem. Rev. 107 (2007), 641–662. 32. Garmanova, T., Larina, N., Pollution Monitoring of Snow Cover Dust Aerosols in Tyumen, vol. 7, 2012, Tyumen State University Herald, 49–55. 33. Gaskova, O.L., Behavior of heavy metals in the drainage unloading area of the Salagaev tailing dump (Salair, Kemerovo region). Geochemistry 1 (2004), 70–81 (in Russian). 34. Grebenshchikova, V.I., Pastukhov, M.V., Akimov, M.S., Migration of mercury with atmospheric precipitation in the Baikal region//Mercury in the biosphere: ecological and geochemical aspects. Proceedings of the International Symposium. - Moscow, Institute of Geochemistry and Analytical Chemistry. V.I. Vernadsky Institute of the Russian Academy of Sciences, September 7-9. 2010, 2010, GEOKHI RAS, Moscow, 104–109 (in Russian). 35. Gustaytis, M.A., Lazareva, E.V., Bogush, A.A., Shuvaeva, O.V., Shcherbakova, I.N., Polyakova, E.V., Badmaeva, Z.O., Anoshin, G.N., Distribution of mercury and its species in the zone of sulfide tailing. Dokl. Earth Sci. 432:2 (2010), 778–782. 36. Gustaytis, M.A., Lazareva, E.V., Myagkaya, I.N., Bogush, A.A., Shuvaeva, O.V., 2013. Mercury species in solid matter of dispersion of the Ursk tailing dispersion train (Ursk village, Kemerovo region, Russia). 22–27 September, 2012. Rome, Italy. The International Conference on Heavy Metals in the Environment (16th ICHMET) Abstracts. The E3S Web of Conferences Journal. EDP Sciences 1, pp. 19007–19011. 37. Gustaytis, M.A., Myagkaya, I.N., Shcherbov, B.L., Lazareva, E.V., Migration of Mercury in Technogenic Systems with Extremely High Contents (Ursky Tailing Dump, Kemerovo Region)//Materials of the All-Russian Scientific Conference with International Participation “Noble Rare and Radioactive Elements in Ore-forming Systems”, Novosibirsk, Russia, October 28-30, 2014, 184–190 (in Russian). 38. Gustin, M., Jaffe, D., Reducing the uncertainty in measurement and understanding of mercury in the atmosphere. Environ. Sci. Technol. 44 (2010), 2222–2227. 39. Hall, B., Bloom, N.S., Munth, e.J., An experimental study of two potential methylation agents of mercury in the atmosphere: CH3I and DMS. Water Air Soil Pollut. 80 (1995), 337–341. 40. Hammerschmidt, C.R., Lamborg, C.H., Fitzgerald, W.F., Aqueous phase methylation as a potential source of methylmercury in wet deposition. Atmos. Environ. 41 (2007), 1663–1668. 41. Howe, K.J., Clark, M.M., Fouling of microfiltration and ultrafiltration membranes by natural waters. Environ. Sci. Technol. 36:16 (2002), 3571–3576. 42. ISO 12846, Water Quality –Determination of Mercury – Method Using Atomic Absorption Spectrometry (AAS) with and without Enrichment. 2012. 43. Ivanov, A.V., Bazarova, V.B., Chemical weathering of pyrite with water and various solutions at positive and negative temperatures. Migration of Elements in Permafrost, 1985, Nauka, Novosibirsk, 115–124 (in Russian). 44. Jambor, J.L., Mineralogy of sulfide rich tailings and their oxidation products. Environmental Geochemistry of Sulfide Mine-Wastes. Jambor, J.L., Blowes, D.W., (eds.) Waterloo, Ontario, Canada. Mineral. Assoc. of Canada, Short Course Series, vol. 22, 1994, 59–102. 45. Jernelov, A., Wallin, T., Air-borne mercury fall out on snow around five Swedish chlor-alkali plants. Atmos. Environ. 7 (1973), 209–214 Pergamon Press. 46. Johannessen, M., Henriksen, A., Chemistry of snow melt water: changes in concentration during melting. Water Resour. Res. 14 (1978), 615–619. 47. Khmelev, V.A., Tanasienko, A.A., Soil Resources of Kemerovo Region and Basis Their Conservation. Novosibirsk, 2013, 477 (in Russian). 48. Khodzher, T.V., Semenov, M.Yu., Obolkin, V.A., Domysheva, V.M., Golobokova, L.P., Kobeleva, N.A., Netsvetaeva, O.G., Potemkin, V.L., Sergeeva, M.V., Monitoring of fallout in the Baikal region. Chem. Sustain. Dev. 10 (2002), 699–705 (in Russian). 49. Kirillov, M.V., Bortnikova, S.B., Gaskova, O.L., Authigenic gold formation in the cyanidation tailings of gold-arsenopyrite-quartz ore of Komsomolsk deposit (Kuznetski Alatau, Russia). Environ. Earth Sci., 75(13), 2016, 11 Article number 1050. 50. Kirk, J.L., Louis, V. L. St., Sharp, M.J., Rapid reduction and reemission of mercury deposited into snowpacks during atmospheric mercury depletion events at Churchill, Manitoba, Canada. Environ. Sci. Technol. 40:24 (2006), 7590–7596, 10.1021/es061299. 51. Korzhova, E.N., Kuznetsova, O.V., Smagunova, A.N., Stavitskaya, M.V., Determination of inorganic pollutants in atmospheric aerosols. J. Anal. Chem. 66:3 (2011), 222–240. 52. Kuhn, M., The nutrient cycle through snow and ice, a review. Aquat. Sci. 63 (2001), 150–167. 53. Lacelle, D., Doucet, A., Clark, I.D., Lauriol, B., Acid drainage generation and seasonal recycling in disturbed permafrost near Eagle Plains, northern Yukon Territory, Canada. Chem. Geol. 243:1–2 (2007), 157–177. 54. Lalonde, A.D., Poulain, A.J., Amyot, M., The role of mercury redox reactions in snow on snow-to-air mercury transfer. Environ. Sci. Technol. 36 (2002), 174–178. 55. Larose, C., Dommergue, D., Angel, M., Cossa, D., Averty, B., Marusczak, N., Soumis, N., Scheider, D., Ferrari, C., Springtime changes in snow chemistry lead to new insights into mercury methylation in the Arctic. Geochem. Cosmochim. Acta 74 (2010), 6263–6275. 56. Lazareva, E.V., Tsimbalist, V.G., Shuvaeva, O.V., Arsenic speciation in the tailings impoundment of a gold recovery plant in Siberia. Geochem. Explor. Environ. Anal. 2:3 (2002), 263–268. 57. Lei, Y.D., Wania, F., Is rain or snow a more efficient scavenger of organic chemicals. Atmos. Environ. 38 (2004), 3557–3571. 58. Lin, C.-J., Pehkonen, S.O., The chemistry of atmospheric mercury: a review. Atmos. Environ. 33 (1999), 2067–2079. 59. Loseto, L.L., Lean, D.R.S., Siciliano, S.D., Snowmelt sources of methylmercury to High Arctic ecosystems. Environ. Sci. Technol. 38 (2004), 3004–3010. 60. Luptakova, A., Ubaldin, i.S., Macingova, E., Fornari, P., Giuliano, V., Application of physical-chemical and biological-chemical methods for heavy metals removal from acid mine drainage. Process Biochem. 47:11 (2012), 1633–1639. 61. Magiera, T., Jablonska, M., Strzyszcz, Z., Rachwal, M., Morphological and mineralogical forms of technogenic magnetic particles in industrial dusts. Atmos. Environ. 45 (2011), 4281–4290. 62. Marescotti, P., Carbone, C., Comodi, P., Frondini, F., Lucchetti, G., Mineralogical and chemical evolution of ochreous precipitates from the Libiola Fe-Cu-sulfide mine (Eastern Liguria, Italy). Appl. Geochem. 27:3 (2012), 577–589. 63. Markovich, T.I., The special features of the kinetics of oxidation of divalent iron during sulfuric acid leaching of pyrrhotine with the participation of nitrous acid. Russ. J. Phys. Chem. 83:1 (2009), 25–28. 64. Marusczak, N., Larose, C., Dommergue, D., Yumvihoze, E., Lean, D., Nedjai, R., Ferrari, C., Total mercury and methylmercury in high altitude surface snow from the French Alps. Sci. Total Environ. 409 (2011), 3949–3954. 65. Mitra, S., Mercury in the Ecosystem. 1986, Trans. Tech. Publications, Stafa-Zurich, Switzerland, 327. 66. Myagkaya, I.N., Lazareva, E.V., Gustaitis, M.A., Zayakina, S.B., Polyakova, E.V., Zhmodik, S.M., Gold in the sulfide waste-peat bog system as a behavior model in geological processes. Dokl. Earth Sci. 453:1 (2013), 1132–1136. 67. Myagkaya, I.N., Lazareva, E.V., Gustaytis, M.A., Zhmodik, S.M., Gold and silver in a system of sulfide tailings. Part 2: reprecipitation on natural peat. J. Geochem. Explor. 165 (2016), 8–22. 68. Myagkaya, I.N., Lazareva, E.V., Gustaytis, M.A., Zhmodik, S.M., Gold and silver in a system of sulfide tailings. Part 1: migration in water flow. J. Geochem. Explor. 160 (2016), 16–30. 69. Outridge, P.M., Macdonald, R.W., Wang, F., Stern, G.A., Dastoor, A.P., A mass balance inventory of mercury in the Arctic Ocean. Environ. Chem. 5:2 (2008), 89–111. 70. Panikov, Ya. V., Andryushchenko, V.P., Dyukov, A.N., Erosion Processes at the Hydrotrain Berezovii Log of the Kursk Magnetic Anomaly and Their Control. 1984, Plants and Industrial Environment, Sverdlovsk, 115–120 (in Russian). 71. Petrukhin, O.M., Analiticheskaya Khimiya. Khimicheskie Metody Analiza. 1992, (Analytical Chemistry: Chemical Methods of Analysis), Khimiya, Moscow, 400 p (in Russian). 72. Ptitsyn, A.B., Pavlyukova, V.A., Epova, E.S., Markovich, T.I., Cryogeochemical processes in the oxidation zone of sulfide deposits: experimental data. Dokl. Earth Sci. 411:9 (2006), 1398–1400. 73. Ptitsyn, A.B., Pavlyukova, V.A., Epova, E.S., Markovich, T.I., Modeling cryogeochemical processes in the oxidation zone of sulfide deposits with the participation of oxygen-bearing nitrogen compounds. Geochem. Int. 45:7 (2007), 726–731. 74. Reference Book on the Climate of the USSR. 1977. Novosibirsk: Issue 20, part 2, 378 p. (in Russian). 75. Revich, B.A., Sayet, Yu.E., Yanin, E.P., Geochemistry of the Environment. M.: Nedra. 1990, 335 (in Russian). 76. Rieuwerts, J.S., Mighanetara, K., Braungardt, C.B., Rollinson, G.K., Pirrie, D., Azizi, F., Geochemistry and mineralogy of arsenic in mine wastes and stream sediments in a historic metal mining area in the UK. Sci. Total Environ. 472 (2014), 226–234. 77. Romanova, T.E., Shuvaeva, O.V., Fractionation of mercury in water hyacinth and pondweed from contaminated area of gold mine tailing. Water Air Soil Pollut. 227:6 (2016), 1–9. 78. Romanova, T.E., Shuvaeva, O.V., Belchenko, L.A., Phytoextraction of trace elements by water hyacinth in contaminated area of gold mine tailing. Int. J. Phytoremediation 18:2 (2016), 190–194. 79. Salo, H., Berisha, A.-K., Mäkinen, J., Seasonal comparison of moss bag technique against vertical snow samples for monitoring atmospheric pollution. J. Environ. Sci. 41 (2016), 128–137. 80. Sarmiento, A.M., Del Valls, A., Nieto, J.M., Salamanca, M.J., Caraballo, M.A., Toxicity and potential risk assessment of a river polluted by acid mine drainage in the Iberian Pyrite Belt (SW Spain). Sci. Total Environ. 409:22 (2011), 4763–4771. 81. Sarp, H., Birch, W.D., Hlava, P.F., Pring, A., Sewell, D.K., Nickel, E.H., Perroudite, a new sulfide-halide of Hg and Ag from Cap-Garonne, var, France, and from broken Hill, New South Wales, and Coppin pool, western Australia. Am. Mineral. 72 (1987), 1251–1256. 82. Saryg-ool, B.Yu., Myagkaya, I.N., Kirichenko, I.S., Gustaytis, M.A., Shuvaeva, O.V., Zhmodik, S.M., Lazareva, E.V., Redistribution of elements between wastes and organic-bearing material in the dispersion train of gold-bearing Sulfide tailings: Part I. Geochem. Mineral. Sci. Total Environ. 581–582 (2017), 460–471. 83. Seal, R.R., Hammarstrom, J.M., Geoenvironmental models of mineral deposits: examples from massive sulfide and gold deposits. Environmental Aspects of Mine Wastes. Jambor J.L., Blowes D.W., Ritchie A.I.M, (eds.) Mineral. Associat. of Canada, vol. 31, 2003, 11–50. 84. Sevillano, G.C., Rebollar, M.C., Viñals Olià, J., Presencia en Localidades Españolas de Perroudita, Hg5Ag4S5(I,Br)2Cl2, un Mineral “Raro” que Es Probablemente Frecuente. Conf. MACLA Rev. Soc. Esp. Mineral. 15 (2011), 45–46 (in Spanish). 85. Shatilov, A.Yu., Material Composition and Geochemical Characteristics of Atmospheric Deposition in the Ob Basin: Thesis Abstract. Tomsk., 2001, 24 (in Russian). 86. Shcherbakova, I.N., Gustaitis, M.A., Lazareva, E.V., Bogush, A.A., Migration of heavy metals (Cu, Pb, Zn, Fe, Cd) in the aureole of scattering at the Urskoye tailing dump (Kemerovo Region). Chem. Sustain. Dev. 18 (2010), 535–547. 87. Sheoran, A.S., Sheoran, V., Heavy metal removal mechanism of acid mine drainage in wetlands: a critical review. Miner. Eng. 19:2 (2006), 105–116. 88. Shiltsova, G.V., Lastochkina, V.G. 2006. Influence of the canopy of pine and birch forests on the chemical composition of precipitation in the “Kivach” Reserve, Proc. Karel. Sci. Center Russ. Acad. Sci. Petrozavodsk, Issue. 10. pp. 180–184. (in Russian). 89. Siciliano, S.D., O'Driscoll, N.J., Tordon, R., Hill, J., Beauchamp, S., Lean, D.R.S., Abiotic production of methylmercury by solar radiation. Environ. Sci. Technol. 39 (2005), 1071–1077. 90. Sidenko, N.V., Mobility of heavy metals in self-burning waste heaps of the zinc smelting plant in Belovo (Kemerovo Region, Russia)/N.V. Sidenko, R. Giere, S.B. Bortnikova, F. Cottard, N.A. Palchik. J. Geochem. Explor. 74:1–3 (2001), 109–125. 91. Sidenko, N.V., Lazareva, E.V., Bortnikova, S.B., Kireev, A.D., Sherriff, B.L., Geochemical and mineralogical zoning of high-sulfide mine-waste at the Berikul mine-site, Kemerovo region, Russia. Can. Mineral. 43:4 (2005), 1141–1156. 92. Siudek, P., Frankowski, M., Siepak, J., Trace element distribution in the snow cover from an urban area in central Poland. Environ. Monit. Assess., 187, 2015, 225. 93. Skov, H., Christensen, J.H., Heidam, N.Z., Jensen, B., Wahlin, P., Geernaert, G., Fate of elemental mercury in the Artcic during atmospheric depletion episodes and the load of atmospheric mercury to the Arctic. Environ. Sci. Technol. 38 (2004), 2373–2382. 94. Smolyakov, B.S., Zhigula, M.V., Badmaeva, Zh.O., Full-scale modeling of pollution of freshwater ecosystems by heavy metals. Russ. J. Gen. Chem. 8:2 (1999), 106–111 (in Russian). 95. Soerensen, A.L., Jacob, D.J., Schartup, A.T., Fisher, J.A., Lehnherr, I., Louis, V. L. St., Heimbürger, L.-E., Sonke, J.E., Krabbenhoft, D.P., Sunderland, E.M., Global Biogeochem. Cycles 30 (2016), 560–575. 96. Takenaka, N., Ueda, A., Maeda, Y., Acceleration of the rate of nitrite oxidation by freezing in aqueous solution. Nature 358:27 (1992), 736–738. 97. Talovskaya, A.V., Filimonenko, E.A., Osipova, N.A., Yazikov, E.G., Mercury in dust aerosols in the territory of Tomsk safety in technoshere., 2, 2012, 30–34 (in Russian). 98. Talovskaya, A.V., Filimonenko, E.A., Osipova, N.A., Lyapina, E.E., Yazikov, E.G., Toxic elements (As, Se, Cd, Hg, Pb) and their mineral and technogenic formations in the snow cover in the vicinity of the industrial enterprises of Tomsk. XVIII International Scientific Symposium in Honour of Academician M. A. Usov: PGON2014 IOP Publishing IOP Conf. Ser. Earth Environ. Sci., 21, 2014, 012042, 10.1088/1755–1315/21/1/012042. 99. Tanasienko, A.A., Chumbaev, A.S., Conditions of the formation of ice barriers in eroded chernozems of Western Siberia. Eurasian Soil Sci. 43:4 (2010), 417–426. 100. Tanasienko, A.A., Yakutina, O.P., Chumbaev, A.S., Snowmelt runoff parameters and geochemical migration of the elements in the dissected forest-steppe of West Siberia. Catena 78 (2009), 122–128. 101. Tranter, M., Brimblecomb, e.P., Davies, T.D., Vincent, C.E., Abrahams, P.W., Blackwood, I., A composition of snowfall, snowpack and meltwater in the Scottish Highlands – evidence for preferential elution. Atmos. Environ. 20 (1986), 517–525. 102. Vasilenko, V.N., Nazarov, I.N., Fridman, Sh.B., Monitoring of Snow Cover Pollution. - L.: Gidrometeoizdat. 1985, 181 (in Russian). 103. Veysseyre, A., Moutard, K., Ferrari, C., Van de Velde, K., Barbante, C., Cozzi, G., Capodaglio, G., Boutron, C., Heavymetals in fresh snow collected at different altitudes in the Chamonix and Maurienne valleys. French Alps. Initial results. Atmos. Environ. 35 (2001), 415–425. 104. Vinals, J., Roca, A., Cruellst, M., Nunez, C., Characterization and cyanidation of Rio Tinto Gossan ores. Can. Metall. Q. 34:2 (1995), 115–122. 105. Wagemann, R., Trebacz, E., Boila, G., Lockhart, W.L., Methylmercury and total mercury in tissues of arctic marine mammals. Sci. Total Environ. 218 (1998), 19–31. 106. Wang, X., Pu, W., Zhang, X., Ren, Y., Huang, J., Water-soluble ions and trace elements in surface snow and their potential source regions across northeastern China. Atmos. Environ. 114 (2015), 57–65. 107. Weber, J.H., Review of possible paths for abiotic methylation of mercury in the aquatic environment. Chemosphere 26 (1993), 2063–2077. 108. Weinbruch, S., Ebert, M., Gorzawski, H., Dirsch, T., Berg, T., Steinnes, E., Characterisation of individual aerosol particles on moss surfaces: implications for source apportionment. J. Environ. Monit. 12 (2010), 1064–1071. 109. Weinbruch, S., Wiesemann, D., Ebert, M., Schütze, K., Kallenborn, R., Ström, J., Chemical composition and sources of aerosol particles at Zeppelin mountain (Ny Ålesund, Svalbard. Blais, J.M., Rosen, M.R., Smol, J.P., (eds.) Book: Environmental Contaminants – Using Natural Archives to Track Sources and Long-trem Trends of Pollution, Edition: Developments in Paleoenvironmental Research 18, Chapter:16, 2012, Springer, 461–499. 110. Xiu, G.L., Cai, J., Zhang, W.Y., Zhang, D.N., Bueler, A., Lee, S.C., Shen, Y., Xu, L.H., Huang, X.J., Zhang, P., An improved dual-stage protocol to preconcentrate mercury from airborne particles for precise isotopic measurement. Atmos. Environ. 43 (2009), 957–966. 111. Yanchenko, N.I., Baranov, A.N., Ershov, V.A., Timkina, E.V., Changing pH and conductivity of the snow cover in the city of Bratsk. Syst. Met. Technol. 3:23 (2014), 190–192. 112. Zhang, Y., Jacob, D.J., Dutkiewicz, S., Amos, H.M., Sunderland, C.J., Biogeochemical drivers of the fate of riverine mercury discharged to the global and Arctic oceans, Global Biogeochem. Cycles, 29, 854–864, Zhiyuan, C., Shichang, K. Dahe, Q. 2009. Seasonal features of aerosol particles recorded in snow from Mt. Qomolangma (Everest) and their environmental implications. J. Environ. Sci. 21 (2015), 914–919. 113. Zosin, A.P., Priimak, T.I., Sulimenko, L.P., Mingaleva, T.A., Analysis of the effect of copper-nickel Works on the State of water resources in Nearest features. Water Resour. 39:5 (2012), 590–599.