Nature of the Color of Borates with "Anti-Zeolite" Structure

Bekker T.B.; Solntsev V.P.; Rashchenko S.V.; Yelisseyev A.P.; Davydov A.V.; Kragzhda A.A; Kokh A.E.; Kuznetsov A.B.; Park S.

doi:10.1021/acs.inorgchem.7b03134

Инд. авторы:	Bekker T.B., Solntsev V.P., Rashchenko S.V., Yelisseyev A.P., Davydov A.V., Kragzhda A.A, Kokh A.E., Kuznetsov A.B., Park S.
Заглавие:	Nature of the Color of Borates with "Anti-Zeolite" Structure
Библ. ссылка:	Bekker T.B., Solntsev V.P., Rashchenko S.V., Yelisseyev A.P., Davydov A.V., Kragzhda A.A, Kokh A.E., Kuznetsov A.B., Park S. Nature of the Color of Borates with "Anti-Zeolite" Structure // INORGANIC CHEMISTRY. - 2018. - Vol.57. - Iss. 5. - P.2744-2751. - ISSN 0020-1669.
Внешние системы:	DOI: 10.1021/acs.inorgchem.7b03134; РИНЦ: 35507541; PubMed: 29457896; SCOPUS: 2-s2.0-85042925257; WoS: 000427094000048;
Реферат:	eng: Crystals of the MnxBa12(BO3)(8-2x)F-8x phase were grown from a high-temperature solution. This new fluoride borate is built of positively charged [Ba-12(BO3)(6)](6+) blocks, the so-called "anti-zeolite" pattern. Using X-ray single-crystal diffraction, the bulk atomic arrangement in the centrosymmetric tetragonal unit cell in I4/mcm could be elucidated. Crystals of the (MnF6)(4-) group-containing solid solution MnxBa12(BO3)(8-2x)F-8x are dark brown in color in contrast to the differently colored crystals of (LiF4)(3-) group-containing "anti-zeolite" LiBa12(BO3)(7)F-4 (P4(2)bc). According to the electron spin resonance and optical spectroscopic investigation, the absorption spectrum of LiBa12(BO3)(7)F-4 crystals results from the absorption of light by both exciton and free charge carriers and can be tuned by varying the initial composition of the high-temperature solution.
Ключевые слова:	ELECTRONS; OPTICAL-PROPERTIES; CRYSTAL; GROWTH;
Издано:	2018
Физ. характеристика:	с.2744-2751
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