Инд. авторы:	Sokol A.G., Tomilenko A.A., Bul'bak T.A., Sobolev N.V.
Заглавие:	Synthesis of Hydrocarbons by CO2 Fluid Conversion with Hydrogen: Experimental Modeling at 7.8 GPa and 1350 degrees C
Библ. ссылка:	Sokol A.G., Tomilenko A.A., Bul'bak T.A., Sobolev N.V. Synthesis of Hydrocarbons by CO2 Fluid Conversion with Hydrogen: Experimental Modeling at 7.8 GPa and 1350 degrees C // Doklady Earth Sciences. - 2017. - Vol.477. - Iss. 2. - P.1483-1487. - ISSN 1028-334X. - EISSN 1531-8354.
Внешние системы:	DOI: 10.1134/S1028334X17120285; РИНЦ: 32488938; WoS: 000419076000024;
Реферат:	eng: Synthesis of hydrocarbons by the interaction of a CO2 fluid with hydrogen mantle domains has been simulated in an experiment at 7.8 GPa and 1350 degrees C. The synthesized fluid contains mainly aldehydes; lower amounts of ketones, alcohols, esters, and ethers; as well as noticeable amounts of isobutane and butane, alkenes, arenes, and polycyclic aromatic and heterocyclic hydrocarbons. The fluid is compositionally close to volatiles found in inclusions from mantle olivines and picroilmenites.
Ключевые слова:	AGES; ORIGIN; STABILITY; CONSTRAINTS; GAS; DIAMOND FORMATION; VOLATILE COMPONENTS; YAKUTIAN KIMBERLITES; METHANATION; CHROMATOGRAPHY-MASS SPECTROMETRY;
Издано:	2017
Физ. характеристика:	с.1483-1487
Цитирование:	1. W. Martin, J. Baross, D. Kelley, and M. J. Russell, Nat. Rev. Microbiol. 6, 805-814 (2008). 2. S. L. Miller, Science 117, 528-529 (1953). 3. J. F. Kenney, V. G. Kutcherov, N. A. Bendeliani, and V. A. Alekseev, Proc. Natl. Acad. Sci. U. S. A. 99, 10976-10981 (2002). 4. J. Gao, Y. Wang, Y. Ping, D. Hu, G. Xu, F. Gu, and F. Su, RSC Adv. 2, 2358-2368 (2012). 5. F. M. Schwandner, T. M. Seward, A. P. Gize, K. Hall, and V. J. Dietrich, Geochim. Cosmochim. Acta 101, 191-221 (2013). 6. M. D. Porosoff, B. Yan, and J. G. Chen, Energy Envi-ron. Sci. 9, 62-73 (2016). 7. A.Rohrbach and M. W. Schmidt, Nature 472, 209-212 (2011). 8. A. G. Sokol, G. A. Palyanova, Y. N. Palyanov, A. A. Tomilenko, and V. N. Melenevsky, Geochim. Cosmochim. Acta 73, 5820-5834 (2009). 9. A.G. Sokol, Y. N. Palyanov, A. A. Tomilenko, Bul'bak, and G. A. Palyanova, Earth Planet. Sci. Lett. 460, 234-243 (2017). 10. J. M. Huizenga, A. Crossingham, and F. Viljoen, C. R. Geosci. 344, 67-76 (2012). 11. A.G. Sokol, A. A. Tomilenko, T. A. Bul'bak, G. A. Pal-yanova, Yu. N. Palyanov, and N. V. Sobolev, Dokl. Earth Sci. 474 (2), 680-683 (2017). 12. A.A. Tomilenko, T. A. Bul'bak, M. O. Khomenko, D. V. Kuzmin, and N. V. Sobolev, Dokl. Earth Sci. 468 (2), 626-631 (2016). 13. A.A. Tomilenko, T. A. Bul'bak, L. N. Pokhilenko, D. V. Kuzmin, and N. V. Sobolev, Dokl. Earth Sci. 469 (1), 690-694 (2016). 14. Y. N. Pal'yanov, A. G. Sokol, Y. M. Borzdov, A. F. Kho-khryakov, and N. V. Sobolev, Am. Mineral. 87, 1009-1013 (2002). 15. J. N. Park and E. W. McFarland, J. Catal. 266, 92-97 (2009).