Инд. авторы:	Nadolinny V.A., Yuryeva O.P., Shatsky V.S., Stepanov A.S., Golushko V.V., Rakhmanova M.I., Kupriyanov I.N., Kalinin A.A, Palyanov Y.N., Zedgenizov D.
Заглавие:	New data on the nature of the EPR OK1 and N3 centers in diamond
Библ. ссылка:	Nadolinny V.A., Yuryeva O.P., Shatsky V.S., Stepanov A.S., Golushko V.V., Rakhmanova M.I., Kupriyanov I.N., Kalinin A.A, Palyanov Y.N., Zedgenizov D. New data on the nature of the EPR OK1 and N3 centers in diamond // Applied Magnetic Resonance. - 2009. - Vol.36. - Iss. 1. - P.97-108. - ISSN 0937-9347. - EISSN 1613-7507.
Внешние системы:	DOI: 10.1007/s00723-009-0012-8; SCOPUS: 2-s2.0-70350605490;
Реферат:	eng: The well-known diamond electron paramagnetic resonance (EPR) OK1 and N3 defects are discussed in the context of incorporation of heavy metal, supposedly Ti, in the double semivacancy and substitutional structures, respectively. X-ray phase analysis of inclusions of the growth medium, eclogite, in the diamonds under study shows an atypically high concentration of titanium compounds. To support proposed models, the hyperfine structure (HFS) from 13C in the OK1 center has been analyzed more precisely. The data obtained are consistent with attributing additional satellites around the main EPR lines to HFS from 47Ti and 49Ti. A double semivacancy model describes the directions of g and A tensor components of the OK1 center. The features of infrared and photoluminescence spectra related to the OK1/S1 and N3/440.3 nm centers are presented. © Springer 2009.
Ключевые слова:	Electron paramagnetic resonance; Growth medium; Paramagnetic resonance; Transition metal compounds; Titanium nitride; Titanium; Quantum theory; Paramagnetism; Infrared spectroscopy; Heavy metals; Electron spin resonance spectroscopy; Electron resonance; Diamonds; Diamond deposits; X-ray phase analysis; Tensor components; Photoluminescence spectrum; Hyperfine structure; Eclogites; High concentration;
Издано:	2009
Физ. характеристика:	с.97-108