Инд. авторы: | Osipov A.A., Osipova L.M. |
Заглавие: | Low frequency Raman scattering in the BaO-B2O3 glasses: The effect of temperature |
Библ. ссылка: | Osipov A.A., Osipova L.M. Low frequency Raman scattering in the BaO-B2O3 glasses: The effect of temperature // European Journal of Glass Science and Techology. Part B: Physics and Chemistry of Glasses. - 2015. - Vol.56. - Iss. 2. - P.53-58. - ISSN 1753-3562. |
Внешние системы: | SCOPUS: 2-s2.0-84944097167; |
Реферат: | eng: The low frequency Raman spectra of a series of barium borate glasses (with 20, 25, 30 and 35 mol% BaO) were measured and analysed from room temperature to 500°C. There are two contributions to the low frequency Raman spectra: vibrations (boson peak and low lying vibrational modes) and relaxations (quasi-elastic scatering (QES)). It was found that increasing the BaO content leads to a small shift of the boson peak to higher frequency. An increase in the temperature does not lead to significant changes in the shape of the low frequency envelope or to a change of the boson peak frequency. Nevertheless, an increase in the temperature leads to a growth in the intensity of the low frequency minimum below the boson peak (ω<ωBP). This indicates an increase of the QES contribution to the low frequency spectra. The increase in the QES contribution depends on the glass composition, and increases with increasing BaO content.
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Ключевые слова: | Vibrational modes; Low-frequency spectra; Low-frequency Raman scattering; Low-frequency Raman; Higher frequencies; Glass; Effect of temperature; Barium borate; Raman scattering; Bosons; Barium compounds; Glass compositions; |
Издано: | 2015 |
Физ. характеристика: | с.53-58 |