Инд. авторы:	Rashchenko S.V., Bakakin V.V., Shatskiy A.F., Gavryushkin P.N., Seryotkin Y.V., Litasov K.D.
Заглавие:	Noncentrosymmetric Na2Ca4(CO3)5 Carbonate of 'm13M23XY3Z' Structural Type and Affinity between Borate and Carbonate Structures for Design of New Optical Materials
Библ. ссылка:	Rashchenko S.V., Bakakin V.V., Shatskiy A.F., Gavryushkin P.N., Seryotkin Y.V., Litasov K.D. Noncentrosymmetric Na2Ca4(CO3)5 Carbonate of 'm13M23XY3Z' Structural Type and Affinity between Borate and Carbonate Structures for Design of New Optical Materials // Crystal Growth & Design. - 2017. - Vol.17. - Iss. 11. - P.6079-6084. - ISSN 1528-7483. - EISSN 1528-7505.
Внешние системы:	DOI: 10.1021/acs.cgd.7b01161; РИНЦ: 31067812; SCOPUS: 2-s2.0-85032706398; WoS: 000414506300054;
Реферат:	eng: A number of carbonates with promising optical properties were synthesized during the past decade, proving the potential of carbonate systems as a source of novel optical materials. Here we report a new noncentrosymmetric Na2Ca4(CO3)5 carbonate (P63mc; a = 10.37402(14) Å, c = 6.25935(9) Å) with 'M13M23XY3Z' structural type. This structural type, built upon an M13M23 cationic array with three types of anion-filled voids (X, Y, and Z), can accommodate a variety of cations (alkali, alkaline earth, and rare earth) and anions (carbonate, borate, and halide), as we show by extensive analysis of structures of known compounds, and appears to be very promising for the search of new optical materials. © 2017 American Chemical Society.
Ключевые слова:	Non-centrosymmetric; Alkali halides; Calcium compounds; Negative ions; Alkaline earth; Optical properties; Rare earth compounds; Sodium compounds; Carbonation; Structural type; Optical materials; Carbonate system;
Издано:	2017
Физ. характеристика:	с.6079-6084