Инд. авторы: Vinnik D.A., Mashkovtseva L.S., Gudkova S.A., Zherebtsov D.A., Semisalova A.S., Yakushechkina A.K., Perov N.S., Nemrava S., Niewa R., Isaenko L.I.
Заглавие: Growth, structural and magnetic characterization of zn-substituted barium hexaferrite single crystals
Библ. ссылка: Vinnik D.A., Mashkovtseva L.S., Gudkova S.A., Zherebtsov D.A., Semisalova A.S., Yakushechkina A.K., Perov N.S., Nemrava S., Niewa R., Isaenko L.I. Growth, structural and magnetic characterization of zn-substituted barium hexaferrite single crystals // Materials Chemistry and Physics. - 2015. - Vol.163. - P.416-420. - ISSN 0254-0584. - EISSN 1879-3312.
Внешние системы: DOI: 10.1016/j.matchemphys.2015.07.059; РИНЦ: 24944677; SCOPUS: 2-s2.0-84940462074; WoS: 000365361500048;
Реферат: eng: Zn-doped barium hexaferrite BaFe12-xZnxO19 (0 ≤ x ≤ 0.065) single crystals were grown from carbonate flux at temperatures below 1260 °C in order to study the effect of Zn-substitution on the structural and magnetic properties. Upon increasing Zn-content the lattice parameters increase to a small degree, due to a larger ionic size of Zn2+ as compared to Fe3+. The saturation magnetization and coercivity of the studied crystals turns out to depend very sensitive on the level of Zn-substitution. A considerable coercivity decrease up to 30% was observed for samples with x = 0.065, while the Curie temperature was found to be comparably little influenced, dropping from 455 °C for the undoped compound to 445 °C for the maximum x obtained. We demonstrate the possibility to use the carbonate flux growth method for producing hexaferrite crystals and tune their functional properties via doping with zinc. © 2015 Elsevier B.V. All rights reserved.
Ключевые слова: Zn substitutions; Structural and magnetic properties; Magnetic characterization; Functional properties; Flux-growth method; Coercivity decrease; Barium hexaferrites; Zinc; Saturation magnetization; Materials properties; Magnetism; Magnetic properties; Single crystals; Growth (materials); Ferrite; Doping (additives); Crystal structure; Crystal growth; Coercive force; Barium; Magnetic properties; Magnetic materials; Crystal structure; Crystal growth; Magnetic materials; Zn-substituted;
Издано: 2015
Физ. характеристика: с.416-420