Инд. авторы:	Artem’ev A.V., Doronina E.P., Rakhmanova M.I., Sutyrina A.O., Bagryanskaya I.Y., Tolstoy P.M., Gushchin A.L., Mazur A.S., Gusarova N.K., Trofimov B.A.
Заглавие:	Luminescent CuI thiocyanate complexes based on tris(2-pyridyl)phosphine and its oxide: from mono-, di- and trinuclear species to coordination polymers
Библ. ссылка:	Artem’ev A.V., Doronina E.P., Rakhmanova M.I., Sutyrina A.O., Bagryanskaya I.Y., Tolstoy P.M., Gushchin A.L., Mazur A.S., Gusarova N.K., Trofimov B.A. Luminescent CuI thiocyanate complexes based on tris(2-pyridyl)phosphine and its oxide: from mono-, di- and trinuclear species to coordination polymers // New Journal of Chemistry. - 2016. - Vol.40. - Iss. 12. - P.10028-10040. - ISSN 1144-0546.
Внешние системы:	DOI: 10.1039/c6nj02087a; SCOPUS: 2-s2.0-84999700153;
Реферат:	eng: Tris(2-pyridyl)phosphine oxide reacts with CuSCN to form a variety of luminescent complexes, depending on the specified metal-to-ligand ratio and the solvent used, viz. mononuclear [Cu(N,N′,N′′-Py3P=O)(NCS)], dinuclear (N,N′-Py3P=O)Cu(SCNNCS)Cu[(N,N′-Py3P=O)], their co-crystal (2 : 1, correspondingly) and trinuclear {Cu(NCS)[SCNCu(N,N′,N′′-Py3P=O)]2}. In the solid state, these complexes feature red-orange emission upon UV photoexcitation. The reaction of tris(2-pyridyl)phosphine with CuSCN quantitatively produces an almost insoluble coordination polymer, [Cu(Py3P)NCS]n, which exhibits bright green emission. The synthesized compounds are the first members of the hitherto unknown family of Cu(i) thiocyanate complexes supported by tripodal ligands. © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.
Издано:	2016
Физ. характеристика:	с.10028-10040