Инд. авторы:	Bolotina N.B., Gavryushkin P.N., Korsakov A.V., Rashchenko S.V., Seryotkin Y.V., Golovin A.V., Moine B.N., Zaitsev A.N., Litasov K.D.
Заглавие:	Incommensurately modulated twin structure of nyerereite Na1.64K0.36Ca(CO3)(2)
Библ. ссылка:	Bolotina N.B., Gavryushkin P.N., Korsakov A.V., Rashchenko S.V., Seryotkin Y.V., Golovin A.V., Moine B.N., Zaitsev A.N., Litasov K.D. Incommensurately modulated twin structure of nyerereite Na1.64K0.36Ca(CO3)(2) // Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials. - 2017. - Vol.73. - P.276-284. - ISSN 2052-5206. - EISSN 2052-5192.
Внешние системы:	РИНЦ: 29305104; РИНЦ: 29305104; РИНЦ: 29305104; SCOPUS: 2-s2.0-85017102346; PubMed: 28362292; DOI: 10.1107/S2052520616020680; WoS: 000399007700020;
Реферат:	eng: The incommensurately modulated twin structure of nyerereite Na1.64K0.36Ca(CO3)(2) has been first determined in the (3 + 1)- dimensional symmetry group Cmcm(alpha 00)00s with modulation vector q = 0.383a*. Unit-cell values are a = 5.062 (1), b = 8.790 (1), c = 12.744 (1) angstrom. Three orthorhombic components are related by threefold rotation about [001]. Discontinuous crenel functions are used to describe the occupation modulation of Ca and some CO3 groups. The strong displacive modulation of the O atoms in vertexes of such CO3 groups is described using x- harmonics in crenel intervals. The Na, K atoms occupy mixed sites whose occupation modulation is described in two ways using either complementary harmonic functions or crenels. The nyerereite structure has been compared both with the commensurately modulated structure of K-free Na2Ca(CO3)(2) and with the widely known incommensurately modulated structure of gamma-Na2CO3.
Ключевые слова:	TANZANIA; OLDOINYO-LENGAI; COMPUTING SYSTEM JANA2006; incommensurately modulated structures; X-ray analysis; nyerereite; carbonates; minerals; twinning; VOLCANO;
Издано:	2017
Физ. характеристика:	с.276-284
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