Инд. авторы:	Zedgenizov D.A., Kalinin A.A, Alinina V.V.K., Palyanov Yu.N, Shatsky V.S.
Заглавие:	Nitrogen and hydrogen aggregation in natural octahedral and cuboid diamonds
Библ. ссылка:	Zedgenizov D.A., Kalinin A.A, Alinina V.V.K., Palyanov Yu.N, Shatsky V.S. Nitrogen and hydrogen aggregation in natural octahedral and cuboid diamonds // Geochemical Journal. - 2017. - Vol.51. - Iss. 2. - P.181-192. - ISSN 0016-7002. - EISSN 1880-5973.
Внешние системы:	DOI: 10.2343/geochemj.2.0452; РИНЦ: 29503866; SCOPUS: 2-s2.0-85017103707; WoS: 000404681600005;
Реферат:	eng: Transformations of nitrogen and hydrogen defects in natural octahedral and cuboid diamonds after multi-stage annealing at P = 6 GPa and T = 2200°C are presented. It has been observed that nitrogen aggregation from A- to B-defects in octahedral diamonds has gradually increased. This transformation of nitrogen has proceeded more rapidly in cuboid diamonds. One may confirm that most of the cuboid diamonds characterized by a low nitrogen aggregation state were not annealed over a long period at mantle conditions and their formation occurred shortly before transportation to the Earth's surface. Unlike octahedral diamonds, cuboid diamonds show a considerable increase in the intensity of the primary hydrogen-related peaks after the annealing, thus implying involvement of sites to which the hydrogen can bond and become IR-active, but these sites are simply not available in the octahedral diamonds. The magnitude to which peak 3107 cm-1 is increased after annealing has been found to be correlated with the total nitrogen content in cuboid diamonds. This supports the suggestion that the vibrational system with a primary line at 3107 cm-1corresponds to a C-H vibration bonded to some form of aggregated nitrogen. Copyright © 2017 by The Geochemical Society of Japan.
Ключевые слова:	Hydrogen; HP-HT treatment; Defects; Cuboid; Annealing; Aggregation; Diamond; Nitrogen;
Издано:	2017
Физ. характеристика:	с.181-192
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