Инд. авторы:	Ohira I., Murakami M., Kohara S., Ohara K., Ohtani E.
Заглавие:	Ultrahigh-pressure acoustic wave velocities of SiO2-Al2O3 glasses up to 200 GPa
Библ. ссылка:	Ohira I., Murakami M., Kohara S., Ohara K., Ohtani E. Ultrahigh-pressure acoustic wave velocities of SiO2-Al2O3 glasses up to 200 GPa // Progress in Earth and Planetary Science. - 2016. - Vol.3. - Art.UNSP 18. - ISSN 2197-4284.
Внешние системы:	DOI: 10.1186/s40645-016-0097-2; WoS: 000381924700001;
Реферат:	eng: Extensive experimental studies on the structure and density of silicate glasses as laboratory analogs of natural silicate melts have attempted to address the nature of dense silicate melts that may be present at the base of the mantle. Previous ultrahigh-pressure experiments, however, have been performed on simple systems such as SiO2 or MgSiO3, and experiments in more complex system have been conducted under relatively low-pressure conditions below 60 GPa. The effect of other metal cations on structural changes that occur in dense silicate glasses under ultrahigh pressures has been poorly understood. Here, we used a Brillouin scattering spectroscopic method up to pressures of 196.9 GPa to conduct in situ high-pressure acoustic wave velocity measurements of SiO2-Al2O3 glasses in order to understand the effect of Al2O3 on pressure-induced structural changes in the glasses as analogs of aluminosilicate melts. From 10 to 40 GPa, the transverse acoustic wave velocity (V-S) of Al2O3-rich glass (SiO2 + 20. 5 mol% Al2O3) was greater than that of Al2O3-poor glass (SiO2 + 3.9 mol% Al2O3). This result suggests that SiO2-Al2O3 glasses with higher proportions of Al ions with large oxygen coordination numbers (5 and 6) become elastically stiffer up to 40 GPa, depending on the Al2O3 content, but then soften above 40 GPa. At pressures from 40 to similar to 100 GPa, the increase in V-S with increasing pressure became less steep than below 40 GPa. Above similar to 100 GPa, there were abrupt increases in the P-V-S gradients (dV(S)/dP) at 130 GPa in Al2O3-poor glass and at 116 GPa in Al2O3-rich glass. These changes resemble previous experimental results on SiO2 glass and MgSiO3 glass. Given that changes of dV(S)/dP have commonly been related to changes in the Si-O coordination states in the glasses, our results, therefore, may indicate a drastic structural transformation in SiO2-Al2O3 glasses above 116 GPa, possibly associated with an average Si-O coordination number change to higher than 6. Compared to previous acoustic wave velocity data on SiO2 and MgSiO3 glasses, Al2O3 appears to promote a lowering of the pressure at which the abrupt increase of dV(S)/dP is observed. This suggests that the Al2O3 in silicate melts may help to stabilize those melts gravitationally in the lower mantle.
Ключевые слова:	SPECTROSCOPY; COORDINATION; ALUMINOSILICATE; AL-27 NMR; MAGMA OCEAN; DEEP MANTLE; EARTHS MANTLE; SILICATE MELTS; X-RAY-DIFFRACTION; CORE-MANTLE BOUNDARY; Heterogeneity of Earth's core-mantle boundary; Acoustic wave velocity; High pressure; Brillouin scattering; Glass structure;
Издано:	2016