Инд. авторы:	Sokol E.V., Kokh S.N., Khoury H.N., Seryotkin Y.V., Goryainov S.V.
Заглавие:	Long-term immobilisation of Cd2+ at the Tulul Al Hammam natural analogue site, central Jordan
Библ. ссылка:	Sokol E.V., Kokh S.N., Khoury H.N., Seryotkin Y.V., Goryainov S.V. Long-term immobilisation of Cd2+ at the Tulul Al Hammam natural analogue site, central Jordan // Applied Geochemistry. - 2016. - Vol.70. - P.43-60. - ISSN 0883-2927.
Внешние системы:	DOI: 10.1016/j.apgeochem.2016.05.002; РИНЦ: 27049026; SCOPUS: 2-s2.0-84971290742; WoS: 000377522000004;
Реферат:	eng: The Tulul Al Hammam area in central Jordan is a natural analogue site where to study long-term Cd2+ retention during the weathering of Cd-enriched combustion-metamorphic marbles with clinker-like mineralogy. Natural Cd-rich portlandite (Ca0.67-0.45Cd0.33-0.55)[OH]2 was discovered and characterised by single-crystal XRD, SEM/EDS, and microprobe analyses, and Raman spectroscopy. The Ca[OH]2 - Cd[OH]2 solid solution ((Ca1-xCdx)[OH]2) is isostructural with Ca[OH]2 and β-Cd[OH]2 crystals in the CdI2-type of structure. Cd-rich portlandite is a common secondary phase in slightly altered massive marbles, where it replaces and rims single-crystals of the high-temperature precursor (Ca1-xCdx)O. The Cd:Ca molar ratios of (Ca1-xCdx)[OH]2 are inherited from the precursor phase (Ca1-xCdx)O. Reliable long-term immobilisation of Cd in (Ca1-xCdx)[OH]2 is assumed for pore water pH values from 10.5 up to 12 buffered by C-S-Hs formed mainly during spurrite hydration. The Tulul Al Hammam site may have some bearing on long-term Cd2+ retention in the concrete matrix. © 2016 Elsevier Ltd.
Ключевые слова:	Single crystal XRD; Secondary phase; Portlandite; Natural analogue; Microprobe analysis; Long-term Cd retention; High temperature; Central Jordan; Waste management; Waste incineration; Single crystals; Marble; Crystal structure; Cements; Aluminum; Waste management; Natural analogue; Long-term Cd retention; Central Jordan; Cement; Cd-rich portlandite; Minerals; Calcium;
Издано:	2016
Физ. характеристика:	с.43-60
Цитирование:	1. Abd El-Salaam E.A., Hassan K.M. Active surface centres in a heterogeneous CdO catalyst for ethanol decomposition. Surf. Technol. 1982, 16:121-128. 2. Abed A.M., Arouri K.R., Boreham C.J. Source rock potential of the phosphorite-bituminous chalk-marl sequence in Jordan. Mar. Petrol. Geol. 2005, 22:413-425. 3. Abed A., Sadaqah R. Enrichment of uranium in the uppermost Al-Hisa Phosphorite Formation, Eshidiyya basin, southern Jordan. J. Afr. Earth Sci. 2013, 77:31-40. 4. Achternbosch M., Bräutigam K.-R., Hartlieb N., Kupsch C., Richers U., Stemmermann P. Heavy Metals in Cement and Concrete Resulting from the Co-incineration of Wastes in Cement Kilns with Regard to the Legitimacy of Waste Utilization 2003, 200. Forschungszentrum Karlsruhe in der Helmholtz-Gemeinschaft Wissenschaftliche Berichte FZKA 6923, Umwelt Bundes Amt, Germany. http://www.coprocem.com/documents/uba_karlsruhe.pdf. 5. A Natural Analogue Study of the Maqarin, Hyperalkaline Groundwaters. I Source Term Description and Thermodynamic Database Testing 1992, Nagra, Wettingen, Switzerland, NAGRA Tech. Rep. (NTB 91-10). W.R. Alexander (Ed.). 6. Alexander W.R., Smellie J.A.T. Maqarin Natural Analogue Project: ANDRA, CEA, NAGRA, NIREX and SKB Synthesis Report on Phases I, II and III 1998, 101. Scientific Technical Report NPB 98-08, Nagra, Wettingen, Switzerland. 7. Alexander W.R., Dayal R., Eagleson K., Eikenberg J., Hamilton E., Linklater C.M., McKinley I.G., Tweed C.J. A natural analogue of high pH cement pore waters from the Maqarin area of northern Jordan II: results of predictive geochemical calculations. J. Geochem. Explor. 1992, 46:133-146. 8. Alunno R.V., Medici F. Immobilisation of toxic metals in cement matrices. Cem. Concr. Res. 1995, 25:1147-1152. 9. Askarinejad A., Morsali A. Synthesis of cadmium(II) hydroxide, cadmium(II) carbonate and cadmium(II) oxide nanoparticles; investigation of intermediate products. Chem. Eng. J. 2009, 150:569-571. 10. Atkins M., Beckley A.N., Glasser F.P. Influence of cement on the near field environment and its specific interactions with uranium and iodine. Radiochim. Acta 1988, 44/45:255-261. 11. Atkins M., Glasser F.P. Application of portland cement-based materials to radioactive waste immobilization. Waste Manage. 1992, 12:105-131. 12. Atkinson A., Everitt N.M., Guppy R. Evolution of pH in a Radwaste Repository: Experimental Simulation of Cement Leaching. Report DOE/RW/89/025, Part 1 1989, Department of Environment, London, United Kingdom. 13. Balonis M., Lothenbach B., Le Saout G., Glasser F.P. Impact of chloride on the mineralogy of hydrated Portland cement systems. Cem. Concr. Res. 2010, 40:1009-1022. 14. Bender F. Geologie von Jordanien. Beiträge zur Regionalen Geologie der Erde, Band 7 1968, Gebrüder Bornträger, Berlin. 15. Bentor Y.K., Gross S., Heller L. Some unusual minerals from the ''Mottled Zone'' complex. Israel. Am. Min. 1963, 48:924-930. 16. Berger R., McGregor J. Influence of admixtures on the morphology of calcium hydroxide formed during tricalcium silicate hydration. Cem. Concr. Res. 1972, 2:43-55. 17. Berner U. Evolution of pore water chemistry during degradation of cement in a radioactive waste repository environment. Waste Manage. 1992, 12:201-219. 18. Bertrand G., Dusausoy Y. Affinement de la structure de l'hydroxyde de cadmium β-Cd(OH)2. Compt. Rend. Acad. Sci. 1970, 270:612-615. 19. Burg A., Kolodny Ye, Lyakhovsky V. Hatrurim-2000: the ''Mottled Zone'' revisited, forty years later. Isr. J. Earth Sci. 1999, 48:209-223. 20. Burg A., Starinsky A., Bartov Y., Kolodny Y. Geology of the Hatrurim formation (''Mottled zone'') in the Hatrurim basin. Isr. J. Earth Sci. 1992, 40:107-124. 21. Cartledge F.K., Butler L.G., Chalasani D., Eaton H.C., Frey F.P., Herrera E., Tittlebaum M.E., Yang S.-L. Immobilisation mechanisms in solidification/stabilisation of Cd and Pb salts using Portland cement fixing agents. Environ. Sci. Technol. 1990, 24:867-873. 22. Chen Q.Y., Tyrer M., Hills C.D., Yang X.M., Carey P. Immobilisation of heavy metal in cement-based solidification/stabilisation: a review. Waste Manage. 2009, 29:390-403. 23. Clark I.D., Fritz P., Milodowski A.E., Khoury H.N. Sampling and Analytical Methods in: a Natural Analogue Study of the Maqarin Hyperalkaline Groundwaters 1992, 19-40. Nagra Technical Report 91-10, Wettingen, Switzerland. 24. Conner J.R. Chemical Fixation and Solidification of Hazardous Waste 1990, Van Nostrand Reinhold, New York. 25. Conner J.R., Hoeffner S.L. The history of stabilisation/solidification technology. Crit. Rev. Environ. Sci. Technol 1998, 28:325-396. 26. Cudennec Y., Gérault Y., Lecerf A. The ternary diagram of system Na2O-CdO-H2O at room temperature. Mater. Res. Bul. 1999, 34:1557-1562. 27. Desgranges L., Grebille D., Calvarin G., Chevrier G., Floquet N., Niepce J.-C. Hydrogen thermal motion in calcium hydroxide: Ca(OH)2. Acta Crystallogr. 1993, B49:812-817. 28. Duro L., Bruno J. Natural analogues of nuclear waste repositories: studies and their implications for the development of radionuclide migration models. Radionuclide Behaviour in the Natural Environment: Science, Implications and Lessons for the Nuclear Industry 2012, 411-445. Woodhead Publishing Limited, Cambridge. C. Poinssot, H. Geckeis (Eds.). 29. Elie M., Techer I., Trotignon L., Khoury H., Salameh E., Vandamme D., Boulvais P., Fourcade S. Cementation of kerogen-rich marls by alkaline fluids released during weathering of thermally metamorphosed marly sediments. Part II: organic matter evolution, magnetic susceptibility and metals (Ti, Cr, Fe) at the Khushaym Matruck natural analogue (central Jordan). Appl. Geochem 2007, 22:1311-1328. 30. Fahim R.B., Abd El-Salaam K.M. Surface properties and hydration of cadmium oxide. J. Catal. 1967, 9:63-69. 31. Fernández-González Á., Prieto M., Putnis A., López-Andrés S. Concentric zoning patterns in ctystallizing (Cd,Ca)CO3 solid solutions from aqueous solutions. Mineral. Mag. 1999, 63(3):331-343. 32. Fleurance S. Métallogenèse de l'uranium associée à des processus superficiels: L'exemple de la Jordanie centrale 2012, (PhD thesis), Université de Lorraine, Nancy, France. https://petale.univ-lorraine.fr/notice/view/univ-lorraine-ori-20283?lightbox=true. 33. Fleurance S., Cuney M., Malartre M., Reyx J. Origin of the extreme polymetallic enrichment (Cd, Cr, Mo, Ni, U, V, Zn) of the late Cretaceous-early Tertiary Belqa group, central Jordan. Palaeogeogr. Palaeoclimatol. Palaeoecol. 2013, 369:201-219. 34. Fourcade S., Trotignon L., Boulvais P., Techer I., Elie M., Vandamme D., Salameh E., Khoury H. Cementation of kerogen-rich marls by alkaline fluids released during weathering of thermally metamorphosed marly sediments. Part I: isotopic (C, O) study of the Khushaym Matruk natural analogue (central Jordan). Appl. Geochem 2007, 22:1293-1310. 35. Galan I., Glasser F.P., Baza D., Andrade C. Assessment of the protective effect of carbonation on portlandite crystals. Cem. Concr. Res. 2015, 74:68-77. 36. Galmarini S., Aimable A., Ruffray N., Bowen P. Changes in portlandite morphology with solvent composition: atomic simulations and experiment. Cem. Concr. Res. 2011, 41:1330-1338. 37. Galmarini S., Bowen P. Atomistic simulation of the adsorption of calcium and hydroxyl ions onto portlandite surfaces - towards crystal growth mechanisms. Cem. Concr. Res. 2016, 81:16-23. 38. Gallucci E., Scrivener K. Crystallisation of calcium hydroxide in early age model and ordinary cementitious systems. Cem. Concr. Res. 2007, 37:492-501. 39. Ghoshal T., Kar S., Chaudhuri S. Synthesis of nano and micro crystals of Cd(OH)2 and CdO in the shape of hexagonal sheets and rods. Appl. Surf. Sci. 2007, 253:7578-7584. 40. Glasser F.P. Fundamental aspects of cement solidification and stabilisation. J. Hazard. Mater 1997, 52(2-3):151-170. 41. Goryainov S.V., Krylov A.S., Pan Yu., Madyukov I.A., Smirnov M.B., Vtyurin A.N. Raman investigation of hydrostatic and nonhydrostatic compressions of OH- and F-apophyllites up to 8 GPa. J. Raman Spectrosc. 2012, 43:439-447. 42. Goryainov S.V., Likhacheva A.Y., Rashchenko S.V., Shubin A.S., Afanasiev V.P., Pokhilenko N.P. Raman identification of lonsdaleite in Popigai impactites. J. Raman Spectrosc. 2014, 45:305-313. 43. Grapes R. Pyrometamorphism 2011, Springer, Berlin. second ed. 44. Gross S. The mineralogy of the Hatrurim formation. Isr. Geol. Surv. Isr. Bull. 1977, 70:1-80. 45. Gujar T.P., Shinde V.R., Woo-Young Kim, Kwang-Deog Jung, Lokhande C.D., Joo Oh-Shim Formation of CdO films from chemically deposited Cd(OH)2 films as a precursor. Appl. Surf. Sci. 2008, 254:3813-3818. 46. Hadadin N., Qaqish M., Akawwi E., Bdour A. Water shortage in Jordan-Sustainable solutions. Desalination 2010, 250:197-202. 47. Harutyunyan V.S. Adsorption energy of stoichiometric molecules and surface energy at morphologically important facets of a Ca(OH)2 crystal. Mater. Chem. Phys. 2012, 134:200-213. 48. Herrera E., Tittlebaum M., Cartledge F., Eaton H. Evaluation of the leaching properties of solidified heavy metal wastes. J. Environ. Sci. Health A 1992, 27(4):983-998. 49. Humphries D.W. The Preparation of Thin Sections of Rocks, Minerals and Ceramics. Royal Microscopical Society Microscopy Handbooks 1992, (Book 24), Oxford University Press. 50. Kalinichev A.G., Wang J., Kirkpatrick R.J. Molecular dynamics modeling of the structure, dynamics and energetics of mineral-water interfaces: application to cement materials. Cem. Concr. Res. 2007, 37:337-347. 51. Khoury H. Long-term analogue of carbonation in travertine from Uleimat Quarries, central Jordan. Environ. Earth Sci. 2012, 65:1909-1916. 52. Khoury H., Nassir S. A discussion on the origin of Daba - Siwaqa marble. Dirasat 1982, 9:55-56. 53. Khoury H., Nassir S. High temperature mineralisation in Maqarin area, North Jordan. Neues Jb. Min. Abh 1982, 144:197-213. 54. Khoury H.N., Salameh E., Clark F., Fritz R., Bajjali W., Miolodwski A., Cave M., Alexander W. A natural analogue of high pH waters from the Maqarin area of northern Jordan 1: introduction to the site. J. Geochem. Explor 1992, 46:117-132. 55. Khoury H., Salameh E., Clark I. Mineralogy and origin of surficial uranium deposits hosted in travertine and calcrete from central Jordan. Appl. Geochem 2014, 43:49-65. 56. Khoury H., Sokol E., Clark I. Calcium uranium oxides from Central Jordan: mineral assemblages, chemistry, and alteration products. Can. Mineral. 2015, 53(1):61-82. 57. Khoury H.N., Sokol E.V., Kokh S.N., Seryotkin Y.V., Kozmenko O.A., Goryainov S.V., Clark I.D. Intermediate members of the lime-monteponite solid solutions (Ca1-xCdxO, x = 0.36-0.55): discovery in natural occurrence. Am. Mineral. 2016, 101(1):132-147. 58. Khoury H.N., Sokol E.V., Kokh S.N., Seryotkin Y.V., Nigmatulina E.N., Goryainov S.V., Belogub E.V., Clark I.D. Tululite, Ca14(Fe3+,Al)(Al,Zn,Fe3+,Si, P,Mn,Mg)15O36: a new Ca zincate-aluminate from combustion metamorphic marbles, central Jordan. Min. Petrol 2016, 110(1):125-140. 59. Krupa K.M., Serne R.J. Effects on Radionuclide Concentrations by Cement/ground-water Interactions in Support of Performance Assessment of Low-level Radioactive Waste Disposal Facilities 1998, Report NUREG/CR-6377, Pacific Northwest National Lab, Richland, WA, United States. 60. Lavrent'ev Yu.G., Korolyuk V.N., Usova L.V., Nigmatulina E.N. Electron probe microanalysis of rock-forming minerals with a JXA-8100 electron probe microanalyzer. Russ. Geol. Geophys. 2015, 56(10):1428-1436. 61. CRC Handbook of Chemistry and Physics 1996, CRC Press, Boca Raton, Florida. 76th Edition. D.R. Lide (Ed.). 62. A Natural Analogue Study of Analogue Cement Buffered, Hyperalkaline Groundwaters and Their Interaction with a Repository Host Rock: Phase II. Nirex Science Report, S-98-003 1998, UK Nirex, Harwell, U.K. C.M. Linklater (Ed.). 63. Linklater C.M., Albinsson Y., Alexander W.R., Casas I., McKinley I.G., Sellin P. A natural analogue of high pH cement pore waters from the Maqarin area of northern Jordan: comparison of predicted and observed trace element chemistry of uranium and selenium. J. Contam. Hydrol. 1996, 21:59-69. 64. Macphee D.E., Glasser F.P. Immobilisation science of cement systems. MRS Bull. 1993, 18(3):66-71. 65. Malviya R., Chaudhary R. Factors affecting hazardous waste solidification/stabilisation: a review. J. Hazard. Mater 2006, 137:267-276. 66. McKinley I.G., Alexander W.R. The uses of natural analogue input in repository performance assessment: an overview. Proc. 6th NAWG Workshop, Santa Fe, Sept. 1994. CEC EUR Report EN16761, Luxembourg 1996, 273-282. 67. Miller W.M., Alexander W.R., Chapman N.A., McKinley I.G., Smellie J.A.T. Geological Disposal of Radioactive Wastes and Natural Analogues. Waste Management Series 2000, 2. Pergamon, Amsterdam, The Netherlands. 68. Milodowski A.E., Trotignon L., Khoury H., Salameh E., Arnal N., Bienvenu P., Bulle C., Chenery S.R., Crouzet N., Fontanini L., Hodgkinson E.S., Mäder U., McKervey J., Peycelon H., Pontremol S., Rassineux F., Raynal J., Rose J., Vandamme D., Provitina O., Raimbault L. The analogue cement zone (ACZ), chapter 4. A Natural Analogue Study of Cement Buffered, Hyperalkaline Groundwaters and Their Interaction with a Repository Host Rock IV: an Examination of the Khushaym Matruk (Central Jordan) and Maqarin (Northern Jordan) Sites. NDA-RWMD Technical Report 2011, NDA, Moors Row, UK. A. Pitty, R. Alexander (Eds.). 69. Model S506 Interactive Peak Fit, 2002. Canberra Industries Inc. Canberra. 70. Nakamoto K. Infrared and Raman Spectra of Inorganic and Coordination Compounds 1978, Wiley, New York. third ed. 71. Neall F.M. Modelling of the Near-field Chemistry of the SMA Repository at the Wellenberg Site 1994, Paul Scherrer Institut Report 94-18, Paul Scherrer Institut, Villigen, Switzerland. 72. Ochs M., Mallants D., Wang L. Radionuclide and Metal Sorption on Cement and Concrete 2016, Springer International Publishing, Switzerland. 73. Oswald H.R., Asper R. Bivalent metal hydroxides, chapter. Preparation and Crystal Growth of Materials with Layered Structures 1977, 129-140. Springer, Berlin. R.M.A. Lieth (Ed.). 74. Oxford Diffraction CrysAlisRED 171.37.35 2008, Oxford Diffraction Ltd, Abingdon, England. 75. Phedorin M.A., Bobrov V.A., Chebykin E.P., Goldberg E.L., Melgunov M.S., Filippova S.V., Zolotarev K.V. Comparison of synchrotron radiation X-ray fluorescence with conventional techniques for the analysis of sedimentary samples. Geostand. Geoanal. Res. 2000, 24:205-216. 76. Pomiès M.-P., Lequeux N., Boch P. Speciation of cadmium in cement: Part I. Cd2+ uptake by C-S-H. Cem. Concr. Res. 2001, 31:563-569. 77. Pomiès M.-P., Lequeux N., Boch P. Speciation of cadmium in cement: Part II. C3S hydration with Cd2+ solution. Cem. Concr. Res. 2001, 31:571-576. 78. Poon C.S., Qiao X.C., Lin Z.S. Effects of flue gas desulphurization sludge (FGD) on the pozzolanic reaction of reject fly ash blended cement pastes. Cem. Concr. Res. 2004, 34:1907-1918. 79. Pouchou J.L., Pichoir F. 'PAP' (φρz) procedure for improved quantitative microanalysis. Microbeam Analyses 1985, 104-106. CA San Francisco Press, San Francisco, California. J.T. Armstrong (Ed.). 80. Powell J.H., Moh'd B.K. Evolution of Cretaceous to Eocene alluvial and carbonate platform sequences in central and south Jordan. GeoArabia 2011, 16:29-82. 81. Poole A.B., Sims I. Concrete Petrography, a Handbook of Investigative Techniques 2016, CRC Press, Taylor & Francis Group, London. second ed. 82. Prieto M., Fernández-González Á., Putnis A., Fernández-Díaz L. Nucleation, growth, and zoning phenomena in crystallizing (Ba,Sr)CO3, Ba(SO4,CrO4), (Ba,Sr)SO4, and (Cd,Ca)CO3 solid solutions from aqueous solutions. Geochim. Cosmochim. Acta 1997, 61(16):3383-3397. 83. Ristić M., Popović S., Musić S. Formation and properties of Cd(OH)2 and CdO particles. Mater. Lett. 2004, 58:2494-2499. 84. Ritchie I.M., Bing-An X. The kinetic of lime slaking. Hydrometallurgy 1990, 23:377-396. 85. Salameh E., Alraggad M., Tarawneh A. Natural salinity sources in the groundwaters of Jordan - Importance of sustainable aquifer management. Chem. Erde.-Geochem 2014, 74(4):735-747. 86. Schäffer R., Sass I. The thermal springs of Jordan. Environ. Earth Sci. 2014, 72:171-187. 87. Shatsky V.S., Sitnikova E.S., Koz'menko O.A., Palessky S.V., Nikolaeva I.V., Zayachkovsky A.A. Behavior of incompatible elements during ultrahigh-pressure metamorphism (by the example of rocks of the Kokchetav massif). Russ. Geol. Geophys. 2006, 47:482-496. 88. Maqarin Natural Analogue Study: Phase III. SKB Technical Report 1998, I and II. SKB, Stockholm, Sweden. J.A.T. Smellie (Ed.). 89. Sokol E.V., Novikov I.S., Zateeva S.N., Sharygin V.V., Vapnik Ye Pyrometamorphic rocks of the spurrite-merwinite facies as indicators of discharge zones of hydrocarbons (the Hatrurim Formation, Israel). Dokl. Earth Sci. 2008, 420:608-614. 90. Sokol E., Novikov I., Zateeva S., Vapnik Ye., Shagam R., Kozmenko O. Combustion metamorphism in Nabi Musa dome: new implications for a mud volcanic origin of the Mottled Zone, Dead Sea area. Basin Res. 2010, 22:414-438. 91. Sokol E.V., Gaskova O.L., Kokh S.N., Kozmenko O.A., Seryotkin Yu.V., Vapnik Ye, Murashko M.N. Chromatite and its Cr3+- and Cr6+-bearing precursor minerals from the Nabi Musa Mottled zone complex. Jud. Desert. Am. Mineral. 2011, 96:659-674. 92. Sokol E.V., Kokh S.N., Vapnik Thiéry V., Korzhova S.A. Natural analogues of belite sulfoaluminate cement clinkers from Negev desert. Isr. Am. Mineral. 2014, 99:1471-1487. 93. Sunagawa I. Crystals. Growth, Morphology, and Perfection 2005, Cambridge University Press, Cambridge. 94. Taylor H.F.W. Cement Chemistry 1997, Thomas Telford Services, London. second ed. 95. Techer I., Khoury H.N., Salameh E., Rassineux F., Claude C., Clauer N., Pagel M., Lancelot J., Hamelin B., Jacquot E. Propagation of high-alkaline fluids in an argillaceous formation: case study of the Khushaym Matruk natural analogue (Central Jordan). J. Geochem. Explor 2006, 90:53-67. 96. Tits J., Fujita T., Tsukamoto M., Wieland E. Uranium (VI) uptake by synthetic calcium silicate hydrates. Proceedings of the Material Research Society Symposium 1107 2008, 467-474. 97. Zhang D.E., Xie Q., Cai H.X., Zhang X.B., Li S.Z., Han G.Q., Ying A.L., Chen A.M., Tong Z.W. Synthesis and separation property of flower-like Cd(OH)2 microstructures via a simple solution route. Appl. Surf. Sci. 2010, 256:6224-6227.