Инд. авторы:	Shatskiy A., Yamazaki D., Borzdov Y.M., Matsuzaki T., Litasov K.D., Cooray T., Ferot A., Eiji I.T.O., Tomoo K.
Заглавие:	Stishovite single-crystal growth and application to silicon self-diffusion measurements
Библ. ссылка:	Shatskiy A., Yamazaki D., Borzdov Y.M., Matsuzaki T., Litasov K.D., Cooray T., Ferot A., Eiji I.T.O., Tomoo K. Stishovite single-crystal growth and application to silicon self-diffusion measurements // American Mineralogist. - 2010. - Vol.95. - Iss. 1. - P.135-143. - ISSN 0003-004X. - EISSN 1945-3027.
Внешние системы:	DOI: 10.2138/am.2010.3255; SCOPUS: 2-s2.0-77249100460;
Реферат:	eng: Large single crystals of stishovite were successfully synthesized at 11 GPa from a silica solution in water. The potential of both slow cooling and thermal gradient methods were examined. The thermal gradient method provided crystals of 0.8 × 0.8 × 1.3 mm in size grown at 1350 °C and a thermal gradient of 50 °C/mm using stishovite as a silica source. The use of quartz: as a source resulted in the appearance of numerous stishovite crystals in the solution interior resulting in diminished space for the growth of large crystals. This can be explained by a significant difference in the solubility of metastable quartz and stishovite in water, estimated to be 85.3 and 5.6 wt% SiO2 at 1000 °C and 11 GPa, respectively. Crystals up to 0.8 × 1.3 × 1.5 mm were grown by the slow cooling method in the system SiO2 + 14.7 wt% H2O as temperature was decreased from 1600 to 1000 °C with a cooling rate of 2 °C/min. The size of single crystals obtained was large enough to carry out silicon self-diffusion experiments, which were performed at a pressure of 14 GPa and temperatures from. 1400 to 1800 °C. The lattice diffusion coefficients along the [110] and [001] directions can be expressed as D[110] (m2/s) = 4.10 × 10 -12 exp [-322 (kJ/mol)/RT] and D[001] (mVs) = 5.62 × 1.0-12 exp [-334 (kJ/mol)/RT], respectively, where R is the gas constant and T is the absolute temperature.
Ключевые слова:	stishovite; solubility; silicon; quartz; high pressure; diffusion; crystallography; temperature gradient; Stishovite; Single-crystal growth; Silica solubility; High pressure; Diffusion; Aqueous fluid; crystal structure;
Издано:	2010
Физ. характеристика:	с.135-143