Инд. авторы:	Logvinenko V., Dybtsev D., Fedin V., Drebushchak V.A., Yutkin M.
Заглавие:	The stability of inclusion compounds under heating: Part 2. Inclusion compounds of layered zinc camphorate, linked by linear N-donor ligands
Библ. ссылка:	Logvinenko V., Dybtsev D., Fedin V., Drebushchak V.A., Yutkin M. The stability of inclusion compounds under heating: Part 2. Inclusion compounds of layered zinc camphorate, linked by linear N-donor ligands // Journal of Thermal Analysis and Calorimetry. - 2010. - Vol.100. - Iss. 1. - P.183-189. - ISSN 1388-6150. - EISSN 1572-8943.
Внешние системы:	DOI: 10.1007/s10973-009-0444-2; SCOPUS: 2-s2.0-77951253693;
Реферат:	eng: The thermal decomposition of three inclusion compounds: [Zn 2(camph)2dabco]•DMF•H2O, [Zn 2(camph)2bipy]•3DMF•H2O and [Zn 2(camph)2bpe]•5DMF•H2O was studied in the inert atmosphere. TG and DTG curves confirm multi-step decomposition process, the dehydration being the first step. Thermogravimetric data (obtained at different rates of linear heating) were processed with computer program (with 'Model-free' approach). Kinetic parameters of decomposition were calculated for the DMF multi-step removal, the processes are described by Avrami-Erofeev equations. The connection between the kinetic parameters and structural features of the host frameworks (ligand linker lengths and porous-free volumes) are discussed. © 2009 Akadémiai Kiadó, Budapest, Hungary.
Ключевые слова:	Coordination compounds; Inclusion compounds; Non-isothermal kinetics; 'model-free' kinetics; Computer program; Coordination compounds; Decomposition process; Inclusion compounds; Inert atmospheres; Linear heating; Zinc; Thermogravimetric analysis; Reaction kinetics; Pyrolysis; Light measurement; Ligands; Kinetic parameters; Heating; Thermal decompositions; Structural feature; Non-isothermal kinetic; N-donor ligands; Multi-step; 'Model-free' kinetics; Model free;
Издано:	2010
Физ. характеристика:	с.183-189