Инд. авторы:	Minkov V.S., Goryainov S.V., Boldyreva E.V., Görbitz C.H.
Заглавие:	Raman study of pressure-induced phase transitions in crystals oforthorhombic and monoclinic polymorphs of L -cysteine: Dynamics of the sidechain
Библ. ссылка:	Minkov V.S., Goryainov S.V., Boldyreva E.V., Görbitz C.H. Raman study of pressure-induced phase transitions in crystals oforthorhombic and monoclinic polymorphs of L -cysteine: Dynamics of the sidechain // Journal of Raman Spectroscopy. - 2010. - Vol.41. - Iss. 12. - P.1748-1758. - ISSN 0377-0486. - EISSN 1097-4555.
Внешние системы:	DOI: 10.1002/jrs.2624; РИНЦ: 16707943; SCOPUS: 2-s2.0-79952070736;
Реферат:	eng: The series of phase transitions on increasing pressure and on reversedecompression was followed in crystals of monoclinic and orthorhombic polymorphsof L-cysteine by using Raman spectroscopy, with the samples placed in a diamondanvil cell together to ensure identical pressures on the two samples. Theeffects of hydrostatic pressure on the two polymorphs are shown to be radicallydifferent. Depending on the starting polymorph, different phases are formedunder identical compression/decompression conditions. The effect of pressure onthe monoclinic polymorph was studied for the first time. Phase transitions inmonoclinic L-cysteine (at ∼2.9 and ∼3.9 GPa) are completely reversiblewithout a noticeable hysteresis. The changes in the spectra suggest that theH-bond network is distorted and S - H···O bonding dominatesover S - H···S bonding at high pressures, but themolecular conformations change continuously during these transitions. The dataon the orthorhombic polymorph of L-cysteine show that not only the H-bondnetwork is distorted, but also the conformation of the L-cysteine zwitterionchanges very substantially. The previously observed discrepancy in the resultsrelated to the occurrence of a phase existing between 2.1 and 2.3 GPa reportedby Minkov et al. (J. Phys. Chem. B. 2008; 112, 8851) but not observed by Moggachet al. (Acta Crystallogr. B. 2006; 62, 296) could be interpreted; differentphases can be formed at the same pressure, depending on how this pressure wasreached: on direct compression, or in the compression-decompression- compressioncycle. Copyright © 2010 John Wiley & Sons, Ltd.
Ключевые слова:	Raman spectroscopy; polymorphism; high pressure; amino acid; phase transitions;
Издано:	2010
Физ. характеристика:	с.1748-1758
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