Инд. авторы:	Vasil'chenko D.B., Korenev S.V., Baidina I.A., Drebushchak V.A., Moroz N.K., Kozlova S.G., Ulikhin A.S., Uvarov N.F.
Заглавие:	Proton mobility in complex [RhL 4Cl2]HSO4 • nH2SO4 • mH2O salts (L = Py, γ-picoline)
Библ. ссылка:	Vasil'chenko D.B., Korenev S.V., Baidina I.A., Drebushchak V.A., Moroz N.K., Kozlova S.G., Ulikhin A.S., Uvarov N.F. Proton mobility in complex [RhL 4Cl2]HSO4 • nH2SO4 • mH2O salts (L = Py, γ-picoline) // Russian Journal of Electrochemistry. - 2011. - Vol.47. - Iss. 5. - P.631-636. - ISSN 1023-1935.
Внешние системы:	DOI: 10.1134/S102319351105017X; SCOPUS: 2-s2.0-79958109359;
Реферат:	eng: The method of deposition from solutions was used to synthesize [RhL 4Cl2]HSO4 • nH2SO4 • mH2O complex salts (L = Py, γ-picoline), n ≈ 0.5-0.6, m ≈ 5-6. According to the data of X-ray phase analysis, the crystal structure of these salts is formed by layers of cations separated by layers consisting of anions molecules of sulfuric acid and water connected through a system of hydrogen bonds. Calorimetric methods were used to study phase transitions and the range of thermal stability of salts. The method of 1H NMR spectroscopy discovered that protons within the {HSO 4 - • nH2SO4 • mH 2O} subsystem featured enhanced conductivity. Conductivity studies showed that trans-[RhL 4Cl2]HSO4 • nH 2SO4 • mH2O samples had high proton conductivity. © 2011 Pleiades Publishing, Ltd.
Ключевые слова:	solid proton electrolytes; Calorimetric methods; Complex salts; Deposition from solutions; Enhanced conductivity; H NMR spectroscopy; proton mobility; X-ray phase analysis; Crystal structure; Hydrogen bonds; Nuclear magnetic resonance spectroscopy; Protons; Rhodium; Rhodium compounds; Chlorine compounds; Thermodynamic stability; Sulfuric acid; Solid electrolytes; Salts; proton mobility; rhodium acidic complex salts; NMR;
Издано:	2011
Физ. характеристика:	с.631-636