Инд. авторы: Bekker T.B., Fedorov P.P., Kokh A.E.
Заглавие: Phase formation in the BaB 2O 4-BaF 2 system
Библ. ссылка: Bekker T.B., Fedorov P.P., Kokh A.E. Phase formation in the BaB 2O 4-BaF 2 system // Crystallography Reports. - 2012. - Vol.57. - Iss. 4. - P.574-578. - ISSN 1063-7745. - EISSN 1562-689X.
Внешние системы: DOI: 10.1134/S1063774512040025; SCOPUS: 2-s2.0-84865643866;
Реферат: eng: It is shown that the BaB 2O 4-BaF 2 system is quasi-binary with the following eutectics coordinates: 760°C, 59 mol % BaF 2, 41 mol % BaB 2O 4. Due to the intense pyrohydrolysis during the growth of β-BaB 2O 4 crystals from the 55.6 mol % BaB 2O 4 -44.4 mol % BaF 2 composition, the Ba5B4O11 compound is formed in the system. This process leads to the cocrystallization of the β-BaB 2O 4 and Ba 5B 4O 11 phases and impedes the formation of high-quality crystals. © Pleiades Publishing, Ltd., 2012.
Ключевые слова: Crystallography; Chemistry; Quasi-binary; Barium compounds; Phase formations; High quality crystals; Cocrystallization; Pyrohydrolysis;
Издано: 2012
Физ. характеристика: с.574-578