Инд. авторы: | Drebushchak V.A., Dementiev S.N., Seryotkin Y.V. |
Заглавие: | Phase transition at thermal dehydration in stilbite |
Библ. ссылка: | Drebushchak V.A., Dementiev S.N., Seryotkin Y.V. Phase transition at thermal dehydration in stilbite // Journal of Thermal Analysis and Calorimetry. - 2012. - Vol.107. - Iss. 3. - P.1293-1299. - ISSN 1388-6150. - EISSN 1572-8943. |
Внешние системы: | DOI: 10.1007/s10973-011-1608-4; SCOPUS: 2-s2.0-84870812734; |
Реферат: | eng: Thermal dehydration of stilbite was investigated by thermogravimetry and in situ X-ray powder diffraction. Sample mass changes continuously over the whole temperature range, with anomaly near 175 °C described in terms of the second-order phase transition with changes in symmetry from F-centered unit cell to A-centered one. This contradicts to the step-wise change in sample mass and the first-order phase transition with symmetry changing from F2/m to Amma reported in literature. The change in the order of the phase transition by means of the changes in experimental techniques is discussed. © Akadémiai Kiadó, Budapest, Hungary 2011.
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Ключевые слова: | X ray powder diffraction; Thermogravimetric analysis; Phase transitions; Diffraction; Unit cells; Thermal dehydration; Temperature range; Stilbite; Situ X-ray powder diffraction; Dehydration; Mass change; First-order phase transitions; Experimental techniques; X-ray powder diffraction; Thermogravimetry; Stilbite; Phase transition; Dehydration; Second-order phase transition; |
Издано: | 2012 |
Физ. характеристика: | с.1293-1299 |