| Инд. авторы: | Krylov A.S., Kolesnikova E.M., Isaenko L.I., Krylova S.N., Vtyurin A.N. |
| Заглавие: | Measurement of Raman-scattering spectra of Rb2KMoO 3F3 crystal: Evidence for controllable disorder in the lattice structure |
| Библ. ссылка: | Krylov A.S., Kolesnikova E.M., Isaenko L.I., Krylova S.N., Vtyurin A.N. Measurement of Raman-scattering spectra of Rb2KMoO 3F3 crystal: Evidence for controllable disorder in the lattice structure // Crystal Growth & Design. - 2014. - Vol.14. - Iss. 3. - P.923-927. - ISSN 1528-7483. - EISSN 1528-7505. |
| Внешние системы: | DOI: 10.1021/cg4008894; SCOPUS: 2-s2.0-84897784916; WoS: 000332684400007; |
| Реферат: | eng: The λ-shaped line width broadening anomalies of octahedron group vibrations in Rb2KMoO3F3 disordered crystal have been revealed in the wide temperature range by Raman technique. The line width of Mo-O and Mo-F vibrations in this crystal is connected with the lattice disorder. The dependence of ordering degree passing the phase transition point history has been discovered. Wide temperature-line width area is found below structural phase transition where different lattice disorder can be obtained at a given temperature by varying the rate of sample cooling. The current study demonstrates the ability of a dynamic temperature regime to control ordering processes in crystals. © 2014 American Chemical Society.
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| Ключевые слова: | Rubidium; Wide temperature ranges; Temperature regimes; Structural phase transition; Raman techniques; Phase transition point; Lattice structures; Lattice disorders; Disordered crystals; Lattice vibrations; |
| Издано: | 2014 |
| Физ. характеристика: | с.923-927 |