Инд. авторы: | Dymshits A.M., Litasov K.D., Shatskiy A., Sharygin I.S., Ohtani E., Suzuki A., Pokhilenko N.P., Funakoshi K. |
Заглавие: | P-V-T equation of state of Na-majorite to 21 GPa and 1673 K |
Библ. ссылка: | Dymshits A.M., Litasov K.D., Shatskiy A., Sharygin I.S., Ohtani E., Suzuki A., Pokhilenko N.P., Funakoshi K. P-V-T equation of state of Na-majorite to 21 GPa and 1673 K // Physics of the Earth and Planetary Interiors. - 2014. - Vol.227. - P.68-75. - ISSN 0031-9201. - EISSN 1872-7395. |
Внешние системы: | DOI: 10.1016/j.pepi.2013.11.005; РИНЦ: 21866967; SCOPUS: 2-s2.0-84895067020; WoS: 000332191800008; |
Реферат: | eng: The P-V-T equation of state (EoS) for Na-majorite at pressures to 21 GPa and temperatures to 1673 K was obtained from in situ X-ray diffraction experiments using a Kawai-type multi-anvil apparatus. Analyses of the room-temperature P-V data to a third-order Birch-Murnaghan EoS yielded ambient unit cell volume, V-0 = 1476 (1) (angstrom(3)); isothermal bulk modulus, K-0,K-300 = 181 (9) GPa; and its pressure derivative, K-0,K-300' = 4.4 (1.2). When fitting a high-temperature Birch-Murnaghan EoS using entire P-V-T data at a fixed V-0 = 1475.88 angstrom(3), K-0,K-300 184 (4) GPa, K-0,K-300' = 3.8 (6), (partial derivative K-0,K-T/partial derivative T)(p) = -0.023 (5) (GPa K-1), and a = 3.17 (16) x 10(-5) K-1, b = 0.16 (26) x 10(-8) K-2, where alpha = a + bT is the volumetric thermal expansion coefficient. Fitting the Mie-Gruneisen-Debye EoS with the present data to Debye temperature fixed at 00 = 890 K yielded Gruneisen parameter, gamma(0) = 1.35 at q = 1.0 (fixed). The new data on Na-majorite were compared with the previous data on majorite type garnets. The compression mechanism of majoritic garnets was described in detail. The entire dataset enabled to examine the thermoelastic properties of important mantle garnets and these data will have further applications for modeling P-T conditions in the transition zone of the Earth's mantle using ultradeep mineral assemblages. (C) 2013 Elsevier B.V. All rights reserved.
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Ключевые слова: | DIAMOND; GARNET; POWDER DIFFRACTION; LATTICE-VIBRATIONS; SOLID-SOLUTION; HIGH-PRESSURES; SYSTEM; MANTLE TRANSITION ZONE; High pressure experiment; X-ray diffraction; Equation of state; Na-majorite; PHASE-RELATIONS; SODIUM; |
Издано: | 2014 |
Физ. характеристика: | с.68-75 |