Инд. авторы:	Seryotkin Y., Bakakin V.
Заглавие:	Influences of extraframework cations on features of natrolite group zeolites: the crystal structure of partly dehydrated K-containing paranatrolite
Библ. ссылка:	Seryotkin Y., Bakakin V. Influences of extraframework cations on features of natrolite group zeolites: the crystal structure of partly dehydrated K-containing paranatrolite // Zeitschrift fur Kristallographie - Crystalline Materials. - 2015. - Vol.230. - Iss. 4. - P.233-242. - ISSN 2194-4946. - EISSN 2196-7105.
Внешние системы:	DOI: 10.1515/zkri-2014-1807; РИНЦ: 24028488; SCOPUS: 2-s2.0-84929012721; WoS: 000353161400005;
Реферат:	eng: The partly dehydrated paranatrolite from the Khibiny massif, Russia, Na1.88K0.22Ca0.06 [Al2.24Si2.76O10]center dot 2.5H(2)O, has a space group F1d1 and the unit cell parameters a = 18.6586(5), b = 18.6536(5), c = 6.64119(13) angstrom, beta = 90.199(2)degrees, and Z = 8. The dominant Na+ cations are located nearby the sodium positions in the natrolite structure. The potassium cations occupy two individual positions. Their different occupancies define the retention of the monoclinic distortion of the structure. H2O molecules statistically occupy eight positions, six being generated with a triple splitting of two positions. Three kinds of main local cation-water assemblages were distinguished, two being similar to the assemblages in the initial high-water paranatrolite. The comparison with the gonnardite and paranatrolite structures determined previously was carried out. Common structural characteristics of natrolite group minerals are suggested from the local water-cation assemblages.
Ключевые слова:	GONNARDITE; OVER-HYDRATION; PRESSURE NEUTRON-DIFFRACTION; water-cation assemblage; paranatrolite; natrolite group; gonnardite; crystal structure; TETRANATROLITE;
Издано:	2015
Физ. характеристика:	с.233-242